A radical cascade process involving the activation of two aliphatic C–H bonds in a series of five elementary steps converts readily available terminal alkynes into functionalized cyclopentylmethyl arylsulfones. The methodology delivers flexible synthetic intermediates and was applied to the preparation of diquinanes and triquinanes possessing a rare ...
Lise Benoist +4 more
wiley +2 more sources
Heterogeneity of iridoid biosynthesis in catmints: Molecular background in a phylogenetic context
Evolutionary gains and losses of key biosynthetic genes likely resulting from multiple independent evolutionary events explain why certain Nepeta (catnip) species produce both the active, cat‐attracting nepetalactones and sugar‐bound iridoids, while others make only the sugar‐bound forms, and some have lost iridoid production entirely.
Tijana Banjanac +15 more
wiley +1 more source
Do Stereoisomers of Homocysteic Acid Exhibit Different Convulsant Action in Immature Rats?
Pavel Mareš +3 more
openalex +1 more source
Darstellung und Schwingungsspektren von Fluoro-Chloro-Iridaten(IV) einschließlich der Stereoisomeren / Preparation and Vibrational Spectra of Fluoro-Chloro-Iridates(IV) Including Stereoisomers [PDF]
D. Tensfeldt, W. Preetz
openalex +1 more source
Complex engineering of Solanum alkaloids structural diversity in Nicotiana benthamiana
Summary Transient expression in Nicotiana benthamiana offers a powerful and versatile platform for rapid production of complex specialized metabolites. Steroidal glycoalkaloids (SGAs) and steroidal saponins produced by members of the Solanaceae family are known for their diverse structures and activities including antimicrobial, anticancer, antiviral ...
Sachin A. Gharat +6 more
wiley +1 more source
Darstellung und Schwingungsspektren von Chloro-Bromo-Platinaten(IV) einschließlich der Stereoisomeren / Preparation and Vibrational Spectra of Chloro-Bromo-Platinates(IV) Including Stereoisomers [PDF]
W. Preetz, Gerhard Rimkus
openalex +1 more source
Front Cover: Reversible Stereoisomer‐Specific Cotton Effect of the Ligand Field Transitions at a Copper(II) Binding Site of the Prion Protein (Eur. J. Inorg. Chem. 2/2022) [PDF]
Lina Rivillas‐Acevedo +4 more
openalex +1 more source
Poly(lactic) acid (PLA) biodegradability in fiber form is relatively unexplored. This study shows that the drawing of the fibers during production affects the mechanical properties but slows down the biodegradation of the PLA. Biodegraded undrawn fibers showed peeling whereas drawn fibers showed crack formation on the surface.
Jose Alejandro Fernandez +2 more
wiley +1 more source

