Results 121 to 130 of about 13,428 (198)
A Straightforward Synthesis of Benzestrol by Matteson Homologation Using Chiral Benzyl Carbamates
Benzestrol can easily be obtained stereoselectively via Matteson reaction using chiral Boronic esters and chiral benzyl carbamates. A straightforward and highly stereoselective synthesis of the non‐steroidal estrogen benzestrol is described based on Matteson homologations.
Max Benjamin Becker, Uli Kazmaier
wiley +1 more source
Catalytic asymmetric construction of remote P or other heteroatom (Si/S) stereogenic axially chiral scaffolds. [PDF]
Liu W, Ling Z, Liu YZ, Deng WP.
europepmc +1 more source
Molecular Networking-Based Annotation of Tuberostemonine Isomers Using MS/MS Spectral Similarity. [PDF]
Peng XT, Li BH, Su C, Zhang C.
europepmc +1 more source
An inexpensive industrial refrigerant, HFO‐1234ze, is transformed into a versatile fluoroalkyl building block via a scalable, solvent‐free protocol. Utilizing the metal‐free photocatalyst 4CzIPN, efficient visible‐light‐induced radical addition to alkynes reveals distinct, substrate‐dependent stereoselectivities.
Bálint Varga +5 more
wiley +1 more source
Borylcyclopropanes: Synthetic Strategies and Applications
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
Unified Synthesis of Unconventional α‐Polyhalogenated Amines Through Hydroaminoalkylation
A unified, redox‐neutral method that transforms alkenes and alkynes into α‐polyhalomethyl amines using stable hemiaminal reagents is reported. This approach enables access to CF3, CF2H, CF2Cl, and CFClH motifs, expanding halogenated amine space with broad substrate scope, functional group tolerance, and applicability to late‐stage modification of drug ...
Angela K. Hofmeister +9 more
wiley +1 more source
Airborne PET nanoplastics alter tobacco's chemical risk. [PDF]
Tan MM +11 more
europepmc +1 more source
Efficient cationic gold(I)‐catalyzed intermolecular cyclopropanation of 7‐alkynylnorbornadiene derivatives has been developed. This methodology offers the synthesis of a new class of norbornene derivatives in high yield with excellent diastereoselectivity.
Kento Ishida +3 more
wiley +1 more source
On Serine Octamer Substitution Reactions. [PDF]
Shira BA, Thomas AKE, Cooks RG.
europepmc +1 more source
A sustainable route to photoresponsive molecular systems is achieved using the bio‐based flavanone (‐)‐isolonchocarpin from Tephrosia vogelii. Through McMurry homocoupling and light‐driven 6‐π‐electrocyclization, an overcrowded alkene and a fluorescent O‐heterocyclic phenanthrene are synthesized.
Deryl H. Limawan +8 more
wiley +1 more source

