Results 131 to 140 of about 13,428 (198)
Impact of stereochemistry in 3D energetic materials science: a case based on peripheral editing of the 2,4,10-trioxaadamantane backbone. [PDF]
Li H +8 more
europepmc +1 more source
Silylium‐Ion‐Initiated Disulfidation of Internal Alkynes With Disulfides
Silylium‐ion initiation enables the disulfidation of internal alkynes with diaryl disulfides. The catalytic turnover is maintained by the sulfonium ion ArS(ArSSAr)+ as a sulfenium‐ion carrier that reacts with an alkyne to form a thiirenium ion. Its ring opening by disulfide addition yields the 1,2‐bis(arylthio)‐substituted alkene product with E:Z > 95 ...
Dáiríne M. Morgan +2 more
wiley +1 more source
Phenol and chromone compounds for <i>in silico</i> inhibition of nsP2 and nsP3 of Chikungunya virus. [PDF]
Oliveira Lima JP +8 more
europepmc +1 more source
A strained macrocycle consisting solely of azulene subunits, named [6]cycloparaazulenylene ([6]CPA), is presented. The macrocycle exhibits a notably narrow HOMO–LUMO gap for a pristine azulene species, strain‐induced red‐shifted absorption, and an unusual tubular packing motif elucidated via single‐crystal XRD.
Clara Douglas +8 more
wiley +1 more source
Chiral Carbohydrate Adducts are Effective for Enantiomeric Ion Mobility Separations. [PDF]
Roberts ND, Nagy G.
europepmc +1 more source
Inositol pyrophosphates are energy‐rich signaling molecules that perform critical functions in cells. Three different families of phosphatases hydrolyze the β phosphate of the inositol pyrophosphate molecules: two have narrow specificities and one is promiscuous.
Ronda J. Rolfes
wiley +1 more source
Convergent Total Synthesis of Caribbean Ciguatoxin C-CTX1 and Its C3-Epimer. [PDF]
Sasaki M +4 more
europepmc +1 more source
Ionic epoxy networks are prepared using ammonium salts as hardeners, leading to a two‐stage curing process with a thermoplastic‐like intermediate. This uncommon behavior enables extrusion and fabrication of thermoplastic prepregs that can be cured into thermoset composites.
Izabela Kurowska +10 more
wiley +1 more source
Alkoxyallenes in Modern Synthesis: Reactivity, Catalysis, and Complexity Generation
The last decade has witnessed a remarkable transformation in alkoxyallene chemistry. Although historically employed as synthetic equivalents of acrolein or as versatile 3C synthons, alkoxyallenes are now increasingly recognized as highly adaptable platforms for synthetic design.
A. Lanfranco +5 more
wiley +1 more source
Synthesis and Characterization of Atropdiastereomeric Macrocyclic Metacyclophanes. [PDF]
Wei S, Chen LY, Li J.
europepmc +1 more source

