Results 51 to 60 of about 13,428 (198)

Stereoisomeric engineering mediated zinc metal electrodeposition: Critical balance of solvation and adsorption capability

Advanced Powder Materials
The exceptional electrochemical performance of zinc anodes is frequently impeded by inadequate deposition kinetics and interfacial chemistry. Herein, we introduce the stereoisomerism to inform the balanced selection of electrolyte additives, taking into ...
Wen Liu, Qiwen Zhao, Ruheng Jiang, Xuyan Ni, Tiancheng You, Canglong Li, Yanzi Deng, Bingang Xu, Yuejiao Chen, Libao Chen   +9 more
doaj   +1 more source

Stereoretentive Nucleophilic Aromatic Substitution Accesses Atropisomeric 4‐Amino‐N‐Arylquinolinium Salts

Chemistry – A European Journal, EarlyView.
Quinolin‐4‐ones were converted to chloroquinolinium salts, allowing formation of axially chiral aminoquinolinium salts via an enantioretentive SNAr reaction with a variety of amine nucleophiles. The salts have a high rotational barrier, with a racemization half‐life of ∼1000s of years.
Darren Holmes, Nia Foster, Saima Ansari, Paul Kavanagh, Paul Dingwall, Peter C. Knipe   +5 more
wiley   +1 more source

Scientific Opinion on Flavouring Group Evaluation 67, Revision 1 (FGE.67Rev.1): Consideration of 40 furan‐substituted aliphatic hydrocarbons, alcohols, aldehydes, ketones, carboxylic acids and related esters, sulfides, disulfides and ethers evaluated by JECFA at the 65th meeting (JECFA, 2006b) and re‐evaluated at the 69th meeting (JECFA, 2009c)

EFSA Journal, 2011
The Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids of the European Food Safety Authority was requested to consider evaluations of flavouring substances assessed since 2000 by the Joint FAO/WHO Expert Committee on Food Additives
EFSA Panel on Food Contact Materials, Enzymes, Flavourings and Processing Aids (CEF)
doaj   +1 more source

Exploring Calixarene‐Based Pseudorotaxane Architectures: Threading Ammonium Axles With an Exo‐Rim π‐Functionalized Calix[6]Arene Macrocycle

Chemistry – A European Journal, EarlyView.
This research presents a novel 1,4‐π‐functionalized calix[6]arene with enhanced interactions with dialkylammonium axles. We investigate threading behavior in CDCl3, highlighting how exo‐rim π‐functionalization affects binding affinity and stereoselectivity.
Veronica Iuliano, Paolo Della Sala, Placido Neri, Donato De Simone, Rocco Del Regno, Margherita De Rosa, Carmine Gaeta, Carmen Talotta   +7 more
wiley   +1 more source

Features of stereoisomerism of uterine contraction in pregnant women with isthmic-cervical insufficiency and its clinical significance

Медицинский вестник Юга России
Objective: to study the features of contractile activity of the right and left sides of the uterus in patients with isthmiccervical insufficiency and uncomplicated pregnancy and to assess the nature of the gestational processes and labor outcomes ...
T. L. Botasheva, O. V. Keller, O. I. Deriglazova, A. N. Rymashevsky, E. Yu. Lebedenko, N. V. Ermolova, A. K. Grigoryan, O. P. Zavodnov   +7 more
doaj   +1 more source

As nove premissas anestesiológicas da Bíblia Las nueve premisas anestesiológicas de la Biblia Nine Biblical anesthetic premises

Revista Brasileira de Anestesiologia, 2003
JUSTIFICATIVA E OBJETIVOS: Os autores fazem uma análise histórica de nove premissas inerentes à prática anestésica que já estão referenciadas na Bíblia há mais de 3.000 anos (Velho Testamento).
Nilton Bezerra do Vale, José Delfino
doaj   +1 more source

Rapid Access to Photoswitchable RNA Binders: Fluorination Enhances Protein Rescue by Exon Inclusion

Chemistry – A European Journal, EarlyView.
An adaptable approach, many light‐switchable RNA binders. We report a versatile strategy for rapidly synthesizing photoswitchable RNA binders. The ligands can target SMN2 pre‐mRNA, restoring the levels of the corresponding protein by exon‐inclusion rescue.
Lei Zhang, Nemanja Djokovic, Alexander Herr, Anna Wacker, Emily Swanson Hay, Daniel Santana, Amanda E. Hargrove, Harald Schwalbe, Katarina Nikolic, Frank Abendroth, Olalla Vázquez   +10 more
wiley   +1 more source

Warum sind Enzyme Makromoleküle?

CHIMIA, 1983
The paper is devoted to the question wheter the macromolecular structure is really essential for the chemical and biological qualities of enzymes. Recognizing that high molecular weight compounds are relevant both in nature and in modern technology, the
P.L. Luisi
doaj   +1 more source

Coordination Chemistry of Boron Subphthalocyanine With BINOL Derivatives: Unexpected Oxidation to Oxa[4]Helicene and Properties of the Resulting Axially Coordinated Complexes Containing Oxa[4]Helicene and/or BINOL Derivatives

Chemistry – A European Journal, EarlyView.
Treatment of BINOL with a boron subphthalocyanine derivative resulted in the formation of a complex coordinated to an oxa[4]helicene derivative, which is generated via a ring‐closure reaction of BINOL. In contrast, treatment of the monomethyl ether of 1,1′‐bi‐2‐naphthol (BINOL) afforded the expected axially coordinated complex.
Shafikul Islam, Kazuyuki Asahi, Hiroyuki Nishikawa, Daiki Tauchi, Masashi Hasegawa, Ken‐ichi Sugiura   +5 more
wiley   +1 more source

Regioselective Aldol Reactions Directed by Charge and Orbital Effects in Cyclic Germyl Dienolates: Synthesis of Three Distinct Regio‐ and Stereoisomers

Chemistry – A European Journal, EarlyView.
Charge and orbital control represent fundamental principles in organic chemistry. In this study, these principles are applied to the aldol reactions of a cyclic Ge‐dienolate. By systematically tuning the charge and orbital distributions of the Ge‐dienolates and their aldehyde reaction partners, regio‐ and stereoselective access to three distinct aldol ...
Taishi Nojima, Akihito Konishi, Makoto Yasuda   +2 more
wiley   +1 more source