Results 241 to 250 of about 30,863 (282)
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Stereoselective synthesis of anamarine
Tetrahedron, 2004A stereoselective synthesis of the naturally occurring, α,β-unsaturated lactone anamarine is described. The key step was a highly stereoselective aldol reaction of a protected erythrulose derivative with a chiral aldehyde. Another relevant step was an asymmetric aldehyde allylation with a chiral allylborane. The lactone ring was made by means of a ring-
Santiago Diaz‐Oltra +4 more
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Isoflurane anesthesia is stereoselective
European Journal of Pharmacology, 1992The anesthetic effects of the (+) and (-) isomers of isoflurane were determined in mice. Like the clinically important racemate, both isomers produced dose-dependent increases in anesthetic sleep time. A statistically significant (P less than 0.005, ANOVA) difference in the potencies of these isomers ((+) greater than (-)) was observed.
B, Harris, E, Moody, P, Skolnick
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Stereoselective Synthesis of (+)-Aspidofractinine
The Journal of Organic Chemistry, 2009We describe the synthesis of (+)-aspidofractinine, the enantiomer of a naturally occurring alkaloid of the kopsane family. Key features of the synthesis include a stereospecific cyanate to isocyanate rearrangement on a chiral scaffold, a ring-closing alkene metathesis to cleave the chiral auxiliary, and a chemoselective cyclopropanation to introduce ...
David, Gagnon, Claude, Spino
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Stereoselective synthesis of (.+-.)-cyanocycline
Journal of the American Chemical Society, 1986D A, Evans, C R, Illig, J C, Saddler
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Reactivity–Stereoselectivity Mapping for the Assembly of Mycobacterium marinum Lipooligosaccharides
Angewandte Chemie - International Edition, 2021Herman Overkleeft +2 more
exaly
Stereoselective aminoacylation of polyribonucleotides
Journal of the American Chemical Society, 1984A T, Profy, D A, Usher
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“A Study in Yellow”: Investigations in the Stereoselectivity of Ene‐Reductases
ChemBioChem, 2022Fabio Parmeggiani +2 more
exaly

