Computational Analysis of the Asymmetric Hydrogenation of γ-Ketoacids: Weak Interactions and Kinetics. [PDF]
Golovanov IS, Pospelov EV.
europepmc +1 more source
Photoredox-controlled chemo-divergent, regio-, and stereoselective difunctionalization of olefins via switchable SO<sub>2</sub> reintegration. [PDF]
Xia J +7 more
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Woollins’ Reagent: A Graphical Review of Its Main Synthetic Uses
João V. X. da Silva +2 more
doaj +1 more source
DFT Insights into NHC-Catalyzed Switchable [3+4] and [3+2] Annulations of Isatin-Derived Enals and N-Sulfonyl Ketimines: Mechanism, Regio- and Stereoselectivity. [PDF]
Yu S +5 more
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Ion‐Pairing and Counterion Effects in Contemporary Photochemistry
Ion‐pairing and counterion effects have emerged as fundamental yet underexplored determinants of photochemical behavior. Far from inert, counterions, and Coulombic interactions modulate excited‐state dynamics, quenching efficiencies, emission, and catalytic pathways.
Matthias Schmitz, Christoph Kerzig
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Bulky alkali metal cations enabled highly efficient iridium-catalyzed asymmetric hydrogenation for C-N axial chirality via dynamic kinetic resolution. [PDF]
Zhao X +8 more
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A C‐2 functionalized l‐iduronic acid derivative was designed and synthesized as a candidate pharmacological chaperone for iduronate‐2‐sulfatase (IDS), the enzyme involved in the lysosomal storage disease MPS II (Hunter syndrome). The synthesis overcomes significant synthetic challenges associated with manipulations of L‐ido scaffolds.
Vaibhavi Nagendra +12 more
wiley +1 more source
Understanding and Enhancing Stereoselective Polymerization Using a Data Science Approach. [PDF]
Kozuszek CT, Sorensen CC, Leibfarth FA.
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The CoE‐AmDH panel enables sustainable access to chiral amines using diverse amine (AmDH) and amino acid dehydrogenases (AADH). Utilizing formate (FDH) or glucose dehydrogenase (GDH) for cofactor regeneration, this study establishes a robust screening platform for mild reductive aminations.
R. Tilly Bradshaw Allen +2 more
wiley +1 more source
Hexafluoroisopropanol-Promoted Stereospecific Glycosylation Enables Efficient Access to N-O-Linked 1,2-<i>cis</i>-2-Amino Glycosides. [PDF]
Cheng Y, Su R, Tao X, Xue XS, Dai Y.
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