Woollins’ Reagent: A Graphical Review of Its Main Synthetic Uses
João V. X. da Silva +2 more
doaj +1 more source
S‐Adenosylmethionine (SAM) hydrolases counter increased SAM epimerisation in thermophilic archaea
S‐Adenosyl‐l‐methionine (SAM) is a vital enzyme cofactor. Epimerisation at the sulfonium centre of biologically active (SS,SCα)‐SAM is driven by heat, yielding biologically inactive (RS,SCα)‐SAM. Here, two novel archaeal SAM hydrolases from the thermophilic Sulfolobus acidocaldarius and the halophilic Haloferax volcanii are shown to cleave (RS,SCα)‐SAM.
Agnes Bartels +7 more
wiley +1 more source
Copper-Catalyzed Asymmetric Hydroboration of Alkynes to C-N Axially Chiral Azaborines via Dynamic Kinetic Resolution. [PDF]
Guo C +6 more
europepmc +1 more source
Sodium Hypochlorite Pentahydrate in Organic Synthesis and Beyond
Sodium hypochlorite pentahydrate emerges as a versatile, stable, and practical oxidant for organic synthesis. This review highlights its unique reactivity, broad synthetic applications, and growing impact on sustainable oxidation chemistry, providing a comprehensive overview of recent advances and future opportunities. Sodium hypochlorite pentahydrate (
Masayuki Kirihara +2 more
wiley +1 more source
PCA-Based Database Mining Enables the Discovery of Bacterial Carbene Transferases for Stereodivergent Cyclopropanation. [PDF]
Kato S +5 more
europepmc +1 more source
Serine Octamer Substitution Reactions With α‐Hydroxy Acids
ABSTRACT Rationale The amino acid serine forms chiral magic number clusters, which can be studied using mass spectrometry (MS). Serine octamer clusters are also known to incorporate one or two nonserine monomers with serine monomers to make up the octamer.
Keerthana Unni +4 more
wiley +1 more source
Regio-, Stereo-, and Enantioselective C(sp<sup>3</sup>)─H Monofluoroalkenylation via Photo-HAT/Nickel Dual Catalysis. [PDF]
Chen Y +6 more
europepmc +1 more source
Stereoselective Prenylation of Aryl- and Heteroaryl Halides: γ-Selective Suzuki-Miyaura Coupling as a Tool for Asymmetric Csp<sup>2</sup>-Csp<sup>3</sup> Cross-Coupling. [PDF]
Pawlowsky C +4 more
europepmc +1 more source
Asymmetric Mannich reaction of aromatic imines with malonates in the presence of multifunctional catalysts. [PDF]
Kriis K +5 more
europepmc +1 more source

