Enhancing Tris(pyrazolyl)borate-Based Models of Cysteine/Cysteamine Dioxygenases through Steric Effects: Increased Reactivities, Full Product Characterization and Hints to Initial Superoxide Formation. [PDF]
Müller L+4 more
europepmc +1 more source
Metal‐covalent organic frameworks (MCOFs) are novel porous materials that exhibit the advantages of covalent and metal‐organic frameworks. However, it is extremely difficult to resolve their atomic structure and better understand their structure‐properties relation. This work utilizes a synergistic combination of advanced microscopy, spectroscopic, and
Seán Hennessey+11 more
wiley +1 more source
NMR investigation of steric effects in alkyl‐ and haloadamantanes [PDF]
Peter Rudolf Seidl+2 more
openalex +1 more source
A novel approach is introduced that leverages polymer phase transitions to modulate brush behavior. The oleophilic bottle brush system exhibits two distinct melting transitions—bulk and surface—enabling a two‐stage swelling and wetting transition.
Luciana Buonaiuto+7 more
wiley +1 more source
London dispersion forces and steric effects within nanocomposites tune interaction energies and chain conformation. [PDF]
Zhang B+5 more
europepmc +1 more source
Modeling Steric and Electronic Effects in 3‐D‐ and 4D‐QSAR Schemes: Predicting Benzoic pKa Values and Steroid CBG Binding Affinities. [PDF]
Jarosław Polański, Andrzej Bąk
openalex +1 more source
Proposing Altermagnetic‐Ferroelectric Type‐III Multiferroics with Robust Magnetoelectric Coupling
Multiferroics are highly sought after for advanced technological applications. Here, a novel class of type‐III multiferroics is proposed, where ferroelectricity and altermagnetism are inherently interlocked by crystal symmetry, setting them apart from conventional multiferroics. The ferroelectric switching is shown to fully invert the spin polarization
Wei Sun+6 more
wiley +1 more source
Theoretical Investigation of the Steric Effects on Alkyne Semihydrogenation Catalyzed by Frustrated Lewis Pairs. [PDF]
Zeiss A, Hartman J, Kelemen S, Ye J.
europepmc +1 more source
Unusual Tethering Effects in the Schmidt Reaction of Hydroxyalkyl Azides with Ketones: Cation—π and Steric Stabilization of a Pseudoaxial Phenyl Group. [PDF]
C. E. Katz, Jeffrey Aubé
openalex +1 more source
The formation of stable clusters of gold nanoparticles with oligonucleotides at different solution conditions is explored. DNA base homogeneity and strand directionality influence the binding with gold nanoparticles leading to interesting clustering behavior that can be relevant for SERS applications.
Shaila Thakur+3 more
wiley +1 more source