Understanding Interfacial Photoswitching Mechanisms in Atomically‐Thin TMD‐Spiropyran Hybrids
Photochromic molecules can effectively modulate the optoelectronic properties of atomically thin transition metal dichalcogenide semiconductors. Spiropyran that switches its chemical configuration upon alternating UV and visible irradiation enables light‐programmable optoelectronic devices.
Sewon Park +8 more
wiley +1 more source
Rigid-flexible heptazine-biguanide frameworks enable fast electron delocalization and low-steric-hindrance ammonium-ion storage. [PDF]
Du W +6 more
europepmc +1 more source
Using steric hindrance to manipulate and stabilize metal halide perovskites for optoelectronics. [PDF]
Miao Y, Chen Y, Chen H, Wang X, Zhao Y.
europepmc +1 more source
Turning Water Into a Tool: From Degradation Pathways to Functional Engineering in Halide Perovskites
Water exhibits a threshold‐dependent dual role in lead halide perovskites, acting either as a degradation trigger or as a powerful tool for defect passivation, recrystallization, and structural engineering. This review discusses how controlled water‐mediated interactions govern stability, dimensionality, and optoelectronic performance, providing ...
Raphaella T. S. Gonçalves +4 more
wiley +1 more source
Lead‐Free Chiral Hybrid Metal Halides for Circularly Polarized Light‐Emitting Diodes
Lead‐free chiral hybrid metal halides provide a versatile platform for realizing chiroptical responses through chiral modulation of metal–halide frameworks with diverse dimensionalities, induces inversion‐symmetry breaking and enables dissymmetric excited‐state transitions toward efficient circularly polarized luminescence and electroluminescence. This
Kun Zhu, Li Wan
wiley +1 more source
Room-temperature photoluminescence in monocarboxylate-protected silver nanoclusters via steric hindrance-induced interfacial structure locking. [PDF]
Jiang W +6 more
europepmc +1 more source
Size matters: Steric hindrance of precursor molecules controlling the evolution of CdSe magic-size clusters and quantum dots. [PDF]
Shen J +6 more
europepmc +1 more source
Introducing a 5‐phenylbenzo[b]thiophene unit into the DABNA core lowers the T1 level, enlarging the ΔEST to suppress TADF. This molecular design preserves narrow deep‐blue emission while drastically reducing triplet‐related degradation. Consequently, the resulting emitter, BN‐TPh‐TPA, delivers a threefold operational lifetime over the TADF‐active t ...
Jihun Hwang +7 more
wiley +1 more source
Steric Hindrance-Driven Closed-Loop Conversion of Acceptor Enables Long-Life and High-Capacity Fluoride-Ion Batteries. [PDF]
Lei M +7 more
europepmc +1 more source
Structure-guided steric hindrance engineering of Bacillus badius phenylalanine dehydrogenase for efficient L-homophenylalanine synthesis. [PDF]
Wu T, Mu X, Xue Y, Xu Y, Nie Y.
europepmc +1 more source

