Results 21 to 30 of about 942 (180)
Could Polyphenols Help in the Control of Rheumatoid Arthritis?
Rheumatoid arthritis (RA) is a chronic, systemic, joint-invading, autoimmune inflammatory disease, which causes joint cartilage breakdown and bone damage, resulting in functional impairment and deformation of the joints. The percentage of RA patients has
Siyun Sung +3 more
doaj +1 more source
The n-butyramido, isobutyramido, benzamido, and furancarboxamido functions profoundly modulate the electronics of the stilbene olefinic and NH groups and the corresponding radical cations in ways that influence the efficiency of the cyclization due ...
Noel Francis Thomas +7 more
doaj +1 more source
Mechanically Interlocked Indigo Photoswitches
By incorporating indigo photoswitches into the axle of a rotaxane, which features a hydrogen bonding macrocycle, we demonstrate improvement in activation wavelength, photostationary states and thermal reversion, an effect that is governed by topologically constrained supramolecular interactions.
Alexander M. Wilmshurst +9 more
wiley +2 more sources
We address the long‐standing challenge of reactivity–selectivity trade‐off by precisely tuning the redox properties of Fe(IV), rather than simply accelerating its formation, to enable chemically efficient and low‐emission water treatment. ABSTRACT High‐valent iron oxo species (Fe(IV)) are attractive for wastewater treatment because of their high ...
Hongyu Zhou +9 more
wiley +2 more sources
From Stilbenes to carbo‐Stilbenes: an Encouraging Prospect
AbstractBeyond previously described carbo‐naphthalene and carbo‐biphenyl, a novel type of bis‐carbo‐benzenic molecules is envisaged from the stilbene parent. The synthesis, structure, spectroscopic and electrochemical properties of two such carbo‐stilbenes are described at complementary experimental and computational DFT levels. In the selected targets,
Zhu, Chongwei +6 more
openaire +4 more sources
T‐Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond
A cationic, structurally constrained stibenium platform mediates anti‐Markovnikov hydrostibination of alkenes via element–ligand cooperativity (ELC), thereby bypassing the need for weak Sb─H bonds. ABSTRACT The hydrostibination of alkenes represents a largely underdeveloped transformation, owing to the intrinsic lability of the required Sb─H reagents ...
Ekta Nag +4 more
wiley +2 more sources
Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
wiley +2 more sources
On the Preparation of Stilbene Crystals [PDF]
A method of preparing large stilbene crystals suitable for use in scintillation counters is presented.
openaire +2 more sources
AASLD practice guidance on drug, herbal, and dietary supplement–induced liver injury
Hepatology, EarlyView.
Robert J. Fontana +6 more
wiley +1 more source
From Berzelius to Hyperspace: Previously Unrecognized Network of Reactivity in Textbook Brominations
Robotic scans across multidimensional condition spaces of classic bromination reactions uncover regions of previously unrecognized reactivity, yielding new major products and novel substitution patterns. Correlation and anticorrelation analyses of product distributions across these hyperspaces enable reconstruction of the underlying mechanistic ...
Yankai Jia +9 more
wiley +2 more sources

