Results 141 to 150 of about 77,925 (335)

Catalysis in Chemical Modification of Proteins

open access: yesChemCatChem, EarlyView.
Catalytic principles of synthetic organic chemistry have been increasingly applied to chemical modification of proteins during the recent years. This review article describes how seven types of catalytic systems —electrocatalysis, photocatalysis, metal catalysis, acid catalysis, organocatalysis, supramolecular catalysis, and heterogeneous catalysis ...
Seiya Ishizawa   +4 more
wiley   +1 more source

Palladium‐Catalyzed [3+2] Cycloadditions of Alkylidenecyclopropanes to Imines: A Direct Approach to Pyrrolidine Scaffolds

open access: yesChemistryEurope, Volume 3, Issue 3, May 2025.
Pd‐catalyzed annulations of ACPs with different C=N partners in both inter‐ and intramolecular ways are described. The methods provide access to pyrrolidines and pyrrolidine‐fused polycyclic systems, featuring β‐exo‐methylene moieties. Preliminary enantioselective variant has been shown by using a chiral phosphoramidite ligand and DFT studies shed ...
Ricardo Rodiño   +3 more
wiley   +1 more source

Carbazole Framework as Functional Scaffold for the Design of Synthetic Receptors

open access: yesChemistry – A European Journal, EarlyView.
Carbazole‐based receptors play a crucial role in supramolecular chemistry, due to their unique geometry, photophysical properties, strong hydrogen bonding features, and versatility. This review examines prominent examples, focusing on how structural modifications shape binding affinity and selectivity for various guests, showcasing the potential of ...
Alessio Carioscia   +6 more
wiley   +1 more source

Preassembly‐Controlled Radical Recombination at Bismuth: Decarboxylative C─N Coupling with Sulfonamides

open access: yesChemistry – A European Journal, EarlyView.
Radical processes involving bismuth hold great potential, but innovative strategies are required to control the reactivity of bismuth intermediates. Herein, we report a direct photochemical decarboxylation with molecular bismuth for C─N coupling of benzylic carboxylic acids and sulfonamides.
Elina K. Taskinen   +3 more
wiley   +1 more source

Synthesis of 2‐(Trifluoromethyl)Azetidines by Strain‐Release Reactions of 2‐(Trifluoromethyl)‐1‐Azabicyclo[1.1.0]Butanes

open access: yesChemistry – A European Journal, EarlyView.
2‐(Trifluoromethyl)‐1‐azabicyclo[1.1.0]butanes, available by diastereoselective cyclopropanation of 2‐(trifluoromethyl)‐2H‐azirines, can be successfully involved in strain‐release ring‐opening processes, as illustrated by their reaction with benzyl chloroformate, trifluoroacetic anhydride or palladium‐catalyzed hydrogenolysis.
Anaïs Scuiller   +7 more
wiley   +1 more source

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