Results 131 to 140 of about 57,978 (298)

Base-Triggered Degradation of Poly(vinyl ester sulfone)s with Tunable Sensitivity

open access: yes, 2016
A series of poly­(vinyl ester sulfone)­s are synthesized and are found to rapidly degrade in the presence of base. Solution phase NMR indicates that the sensitivity of these polymers to base depends on the identity of the ester functional group of the ...
Jeffrey S. Moore (1385685)   +1 more
core   +1 more source

Sulfone-Based Probes Unraveled Dihydrolipoamide S‑Succinyltransferase as an Unprecedented Target in Phytopathogens

open access: yes, 2019
Target validation of current drugs remains the major challenge for target-based drug discovery, especially for agrochemical discovery. The bactericide 0 represents a novel lead structure and has shown potent efficacy against those diseases that are ...
Cai-Guang Yang   +19 more
core   +1 more source

Comparative Study of High Voltage Spinel∥Lithium Titanate Lithium‐ion Batteries in Ethylene Carbonate Free Electrolytes

open access: yesBatteries &Supercaps, Volume 8, Issue 3, March 2025.
FEC and sulfone‐based co‐solvents are investigated as EC‐free electrolytes for LNMO∥LTO cells. FEC‐containing electrolytes demonstrate enhanced electrochemical stability by stabilizing the CEI and SEI layers, mitigating transition metal migration. Conversely, sulfone electrolytes form thinner CEIs and thick, sulfur‐rich SEIs, which are less effective ...
Killian Stokes‐Rodriguez   +6 more
wiley   +1 more source

Molecular Engineering of Sulfone-Xanthone Chromophore for Enhanced Fluorescence Navigation

open access: yes
Enriching the palette of high-performance fluorescent dyes is vital to support the frontier of biomedical imaging. Although various rhodamine skeletons remain the premier type of small-molecule fluorophores due to the apparent high brightness and ...
Xiao-Qi Yu (210227)   +8 more
core   +1 more source

A General Workflow for Tangential Flow Filtration Perfusion Scale‐Up

open access: yesBiotechnology and Bioengineering, EarlyView.
ABSTRACT Tangential flow filtration (TFF) perfusion using hollow‐fiber modules offers substantial advantages over other mammalian cell retention technologies. Recently, increased awareness of Starling flow has helped to enhance filtration performance to similar, or even higher levels compared to alternative technologies.
Patrick Romann   +20 more
wiley   +1 more source

Hybrid Macrocyclic Peptides — Synthetic Strategies to Diversify and Cyclize Peptide Libraries in Phage Display Selections

open access: yesChemistry – A European Journal, EarlyView.
Hybrid macrocyclic peptides unite genetically encoded peptide libraries with the structural complexity of synthetic small molecules. This Review critically analyzes phage‐compatible cyclization and diversification chemistries, highlights emerging opportunities beyond traditional cysteine‐based approaches, and outlines how future advances may enable the
Titia Rixt Oppewal, Clemens Mayer
wiley   +1 more source

Iron-catalyzed fluoroalkylative alkylsulfonylation of alkenes via radical-anion relay

open access: yesNature Communications
Transition metal-catalyzed reductive difunctionalization of alkenes with alkyl halides is a powerful method for upgrading commodity chemicals into densely functionalized molecules.
Xiaoya Hou, Hongchi Liu, Hanmin Huang
doaj   +1 more source

sulfones

open access: yes, 2014
Citation: 'sulfones' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.S06117 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Photoinduced ROS Production by Poly(3‐hexylthiophene) (P3HT) is due to Autoxidation Rather Than Catalysis

open access: yesChemistry – A European Journal, EarlyView.
P3HT is widely treated as a photocatalyst that generates ROS under light. We show otherwise: ROS production comes at the expense of the polymer itself. Photoexcited P3HT acts as a self‐sacrificial photosubstrate, undergoing irreversible autoxidation during light‐driven oxygen reduction—a distinction critical for interpreting its behavior in emerging ...
Roman Gańczarczyk   +2 more
wiley   +1 more source

Redox‐Tuned Oxycarbamates Enable Divergent C─N and C─C Functionalization of Indolizines Under Photoredox Catalysis With Green Light

open access: yesChemistry – A European Journal, EarlyView.
Nonafluoromesitylsulfonyl (Nms)‐substituted oxycarbamates are introduced as redox‐lowered radical precursors for green‐light photoredox synthesis. Selective N─O bond cleavage generates amidyl radicals that directly aminate indolizines in DMF, whereas DMSO promotes 1,2‐hydrogen atom transfer (HAT) to α‐amino carbon‐centered radicals and C─C bond ...
Kevin Klaus Stefanoni, René Wilhelm
wiley   +1 more source

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