Results 1 to 10 of about 20,785 (192)

A reagent to access methyl sulfones [PDF]

Nature Communications
A chemical reagent to access methyl sulfones has been developed. Its reaction with various bis-nucleophiles leads to the rapid formation of previously unknown heteroaromatic methyl sulfones. Analogous strategy can also be used to construct alkyl-, CHF2-,
Yaroslav Poplavskyi, Vasyl Ripenko, Sergei Bova, Angelina Biitseva, Yurii V. Dmitriv, Andrei A. Tolmachev, Iryna V. Sadkova, Iryna Pishel, Oleksii Grygorov, Vo Quang Huy Phan, H. V. Rasika Dias, Pavel K. Mykhailiuk   +11 more
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Copper-catalyzed sulfonylation of alkenes with CH3SSO3Na [PDF]

BMC Chemistry
A successful methodology for the copper-catalyzed dehydrogenated methylsulfonylation of alkenes utilizing CH3SSO3Na in conjunction with hypervalent iodine reagents was successfully established. This method offers a practical avenue to obtain allyl methyl
Xiaoli Chen, Ge Wu
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Direct Synthesis of Allylic Sulfones via Hydrosulfonylation of 1,3-Dienes with Sulfinic Acids [PDF]

Molecules
Catalyst- and additive-free reactions for synthesizing valuable organic compounds have garnered significant attention in the context of sustainable development.
Ke Guo, Shuaichen Zhang, Jing Zhang, Yu Ren, Xiaoqiang Chang, Peng Sun   +5 more
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Hydrogenation of β-Keto Sulfones to β-Hydroxy Sulfones with Alkyl Aluminum Compounds: Structure of Intermediate Hydroalumination Products

Molecules, 2022
β-Hydroxy sulfones are important in organic synthesis. The simplest method of β-hydroxy sulfones synthesis is the hydrogenation of β-keto sulfones. Herein, we report the reducing properties of alkyl aluminum compounds R3Al (R = Et, i-Bu, n-Bu, t-Bu and n-
Michał Kotecki, Zbigniew Ochal, Paweł Socha, Vadim Szejko, Łukasz Dobrzycki, Mariola Stypik, Wanda Ziemkowska   +6 more
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Antimicrobial and Biofilm-Preventing Activity of l-Borneol Possessing 2(5H)-Furanone Derivative F131 against S. aureus—C. albicans Mixed Cultures

Pathogens, 2022
Candida albicans and Staphylococcus aureus are human pathogens that are able to form mixed biofilms on the surface of mucous membranes, implants and catheters.
Rand Sulaiman, Elena Trizna, Alena Kolesnikova, Alsu Khabibrakhmanova, Almira Kurbangalieva, Mikhail Bogachev, Airat Kayumov   +6 more
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Chloroaluminate Ionic Liquid Immobilized on Magnetic Nanoparticles as a Heterogeneous Lewis Acidic Catalyst for the Friedel–Crafts Sulfonylation of Aromatic Compounds

Molecules, 2022
Chloroaluminate ionic liquid bound on magnetic nanoparticles (Fe3O4@O2Si[PrMIM]Cl·AlCl3) was prepared and used as a heterogenous Lewis acidic catalyst for the Friedel–Crafts sulfonylation of aromatic compounds with sulfonyl chlorides or p-toluenesulfonic
Ngoc-Lan Thi Nguyen, Quoc-Anh Nguyen, Tien Khoa Le, Thi Xuan Thi Luu, Kim-Ngan Thi Tran, Phuoc-Bao Pham   +5 more
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A Study on the Chemistry and Biological Activity of 26-Sulfur Analogs of Diosgenin: Synthesis of 26-Thiodiosgenin S-Mono- and Dioxides, and Their Alkyl Derivatives

Molecules, 2022
A chemoselective procedure for MCPBA oxidation of 26-thiodiosgenin to corresponding sulfoxides and sulfone was elaborated. An unusual equilibration of sulfoxides in solution was observed.
Aneta M. Tomkiel, Dorota Czajkowska-Szczykowska, Ewa Olchowik-Grabarek, Lucie Rárová, Szymon Sękowski, Jacek W. Morzycki   +5 more
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Samarium oxide as efficient and non-endangered metal for synthesis of sulfones from sulfides: an elemental sustainability concept

Journal of Taibah University for Science, 2023
Oxidation of sulfide to sulfone is a fundamental process to produce many important pharmaceutical compounds. Formerly, efficient methods have been reported for the synthesis of sulfones from sulfides.
Wei Lam Wan, Preeyashenny A. Jagathison, Noor Fazira Mohd Fauzi, Onn Jew Lee, Poh Wai Chia, Su-Yin Kan   +5 more
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Prospective Approach to the Anaerobic Bioconversion of Benzo- and Dibenzothiophene Sulfones to Sulfide

Molecules, 2019
Sulfur recovery from organic molecules such as toxic sulfones is an actual problem, and its solution through the use of environmentally friendly and nature-like processes looks attractive for research and application.
Olga Senko, Olga Maslova, Marina Gladchenko, Sergey Gaydamaka, Argam Akopyan, Sergey Lysenko, Eduard Karakhanov, Elena Efremenko   +7 more
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Palladium-catalyzed sulfonylative coupling of benzyl(allyl) carbonates with arylsulfonyl hydrazides

Green Synthesis and Catalysis, 2022
An efficient palladium-catalyzed sulfonylative coupling for the synthesis of benzyl(allyl) sulfones from sulfonyl hydrazides and carbonates was developed.
Bozhen Gong, Haibo Zhu, Yishuai Liu, Qian Li, Liu Yang, Guorong Wu, Qiangwen Fan, Zongbo Xie, Zhanggao Le   +8 more
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