Results 11 to 20 of about 275,373 (371)
Acta Crystallographica Section E, 2011 There are two independent molecules in the asymmetric unit of the title compound, C14H14OS, which have asymmetric S—C bonds [1.791 (5) and 1.804 (5) Å in one molecule and 1.798 (5) and 1.804&#
Hai-Yang Liu +3 more
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Current Opinion in Chemical Biology, 2023 In the review, current status of sulfoxides on the pharmaceutical market is discussed. In the first part of the article, natural sulfoxides will be described with a special focus on sulforaphane and amanitin, a mushroom toxin which has been developed as payload in antibody drug conjugates in the possible cancer treatment.
Elżbieta Wojaczyńska +1 more
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Organocatalytic sulfoxidation [PDF]
Tetrahedron, 2021 Treatment of a sulfide with a catalytic amount of a 1,3 diketone in the presence of silica sulfuric acid as a co-catalyst and hydrogen peroxide (50% aq) as the stoichiometric oxidant leads to the corresponding sulfoxide product. The reaction is effective for diaryl, aryl-alkyl and dialkyl sulfides and is tolerant of oxidisable and acid sensitive ...
Stuart C. Davidson +5 more
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Thiol-free chemoenzymatic synthesis of β-ketosulfides
Beilstein Journal of Organic Chemistry, 2019 A preparation of β-ketosulfides avoiding the use of thiols is described. The combination of a multicomponent reaction and a lipase-catalysed hydrolysis has been developed in order to obtain high chemical diversity employing a single sulfur donor.
Adrián A. Heredia +4 more
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Molecules, 2007 A “green” highly selective oxidation of organic sulfides to the corresponding sulfoxides was developed using hydrogen peroxide and glacial acetic acid under transition metal-free and mild conditions.
Farideh Hosseinpoor, Hamid Golchoubian
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An Unexpected Reaction between Diaryliodonium Salts and DMSO
Organics, 2022 Diaryliodonium salts are useful arylating reagents that have been exploited widely. In this Communication, we demonstrate that heating diphenyliodonium triflate in the solvent DMSO leads to an unexpected arylation reaction.
Konrad Kepski, Wesley James Moran
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Molecules, 2015 A pH-dependence of the Brønsted acid-catalyzed oxidation of sulfides to the corresponding sulfoxides with H2O2 is reported for the first time based on our systematic investigation of the catalytic performance of a series of Brønsted acids. For all of the
Hai-Min Shen +8 more
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Revisiting the composition dependence of the properties of water-dimethyl sulfoxide liquid mixtures. Molecular dynamics computer simulations [PDF]
Condensed Matter Physics, 2022, vol. 25, No. 3, 33202, 2022 We have revisited the composition dependence of principal properties of liquid water-DMSO mixtures by using the isobaric-isothermal molecular dynamics computer simulations. A set of non-polarizable semi-flexible models for the DMSO molecule combined with the TIP4P-2005 and TIP4P/$\varepsilon$ water models is considered.
arxiv +1 more source
Synthesis and Evaluation of Novel Benzofuran Derivatives as Selective SIRT2 Inhibitors
Molecules, 2017 A series of benzofuran derivatives were designed and synthesized, and their inhibitory activites were measured against the SIRT1–3. The enzymatic assay showed that all the compounds showed certain anti-SIRT2 activity and selective over SIRT1 and SIRT3 ...
Yumei Zhou +10 more
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A study on tailor made ruthenium sulfoxide complexes: Synthesis, characterization and application [PDF]
Journal of the Serbian Chemical Society, 2015 In this study, a dinucleating spacer incorporating two 2-aminopyridine units has been used to prepare seven novel dinuclear compounds. These molecules were characterized by elemental analyses, conductivity measurements, magnetic susceptibility ...
Mehrotra Ripul +2 more
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