Results 31 to 40 of about 275,373 (371)
Effect of glycerol and dimethyl sulfoxide on the phase behavior of lysozyme: Theory and experiments [PDF]
The Journal of Chemical Physics 136: 015102, 2012, 2011 Salt, glycerol and dimethyl sulfoxide (DMSO) are used to modify the properties of protein solutions. We experimentally determined the effect of these additives on the phase behavior of lysozyme solutions. Upon the addition of glycerol and DMSO, the fluid-solid transition and the gas-liquid coexistence curve (binodal) shift to lower temperatures and the
arxiv +1 more source
Redox Report, 2023 Background Methionine sulfoxide reductases are found in all aerobic organisms. They function in antioxidant defense, cellular regulation by reversible oxidation of methionine in proteins, and in protein structure.
Sujin Park +2 more
doaj +1 more source
Mixtures of Diethyl Sulfoxide and Methanol: Structure and Thermodynamics [PDF]
arXiv, 2021 Mixtures of sulfoxides with molecular solvents possess interesting physical-chemical properties and may have applications in chemical synthesis. Hereby we confirm and rationalize the previously reported excellent miscibility of diethyl sulfoxide (DESO) with methanol (MeOH).
arxiv
Effects of dimethyl sulfoxide on surface water near phospholipid bilayers [PDF]
Biophys. J. (2016) vol. 111, 2481-2491, 2016 Despite much effort to probe the properties of dimethyl sulfoxide (DMSO) solution, effects of DMSO on water, especially near plasma membrane surfaces still remain elusive. By performing molecular dynamics (MD) simulations at varying DMSO concentrations ($X_{\text{DMSO}}$), we study how DMSO affects structural and dynamical properties of water in the ...
arxiv +1 more source
Sulfoxides. V. The Ionization of Sulfoxides in Sulfuric Acid [PDF]
Bulletin of the Chemical Society of Japan, 1965 Abstract Contrary to the earlier claim that diphenyl sulfoxide ionizes in nearly 100% sulfuric acid to give a “diphenyl sulfidonium” ion, which can then return to the original sulfoxide when quenched with water, the 18O tracer experiment and a new set of cryoscopic determinations of a few sulfoxides have revealed that the dissociation of
Shigeru Oae +2 more
openaire +2 more sources
Binary Mixtures of Novel Sulfoxides and Water: Intermolecular Structure, Dynamic Properties, Thermodynamics, and Cluster Analysis [PDF]
, 2018 Senior dialkyl sulfoxides constitute interest in the context of biomedical sciences due to their abilities to penetrate phospholipid bilayers, dissolve drugs, and serve as cryoprotectants. Intermolecular interactions with water, a paramount component of the living cell, determine performance the sulfoxide-based artificial systems in their prospective ...
arxiv +1 more source
Acidity of Strong Acids in Water and Dimethyl Sulfoxide.
Journal of Physical Chemistry A, 2016 Careful analysis and comparison of the available acidity data of HCl, HBr, HI, HClO4, and CF3SO3H in water, dimethyl sulfoxide (DMSO), and gas-phase has been carried out. The data include experimental and computational pKa and gas-phase acidity data from
A. Trummal +4 more
semanticscholar +1 more source
Fast and Selective Post-polymerization Modification of Conjugated Polymers Using Dimethyldioxirane
Frontiers in Chemistry, 2019 Modification of functional groups attached to conjugated polymer backbones can drastically alter the material properties. Oxidation of electron-donating thioalkyl substituents to electron-withdrawing sulfoxides or sulfones is a particularly effective ...
Emmanuel Reichsöllner +7 more
doaj +1 more source
Continuous Bioinspired Oxidation of Sulfides
Molecules, 2020 A simple, efficient, and selective oxidation under flow conditions of sulfides into their corresponding sulfoxides and sulfones is reported herein, using as a catalyst perselenic acid generated in situ by the oxidation of selenium (IV) oxide in a diluted
Francesca Mangiavacchi +4 more
doaj +1 more source
Ice Formation in Model Biological Membranes in the Presence of Cryoprotectors [PDF]
Nuclear Instruments & Methods in Physics Research A 448 (2000)
225-260, 2001 Ice formation in model biological membranes is studied by SAXS and WAXS in the presence of cryoprotectors: dimethyl sulfoxide and glycerol. Three types of phospholipid membranes: DPPC, DMPC, DSPC are chosen for the investigation as well-studied model biological membranes. A special cryostat is used for sample cooling from 14.1C to -55.4C.
arxiv +1 more source