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Aerobic Photocatalysis: Oxidation of Sulfides to Sulfoxides

open access: yesChemPlusChem, 2022
Sulfoxides constitute one of the most important functional groups in organic chemistry found in numerous pharmaceuticals and natural products. Sulfoxides are usually obtained from the oxidation of the corresponding sulfides.
Elpida Skolia   +2 more
exaly   +1 more source
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The Solvent Dimethyl Sulfoxide

Angewandte Chemie International Edition in English, 1967
AbstractThe dipolar aprotic solvent dimethyl sulfoxide is liquid over a wide range of temperatures, is a strong electron donor, and has a high polarity. It is therefore an excellent and selective solvent for many organic and even polymeric compounds, and can enter into H‐bonding and dipole‐dipole association. The structure of dimethyl sulfoxide, with a
D, Martin, A, Weise, H J, Niclas
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Reaction of Arynes with Sulfoxides

Organic Letters, 2015
A S-O bond insertion reaction of sulfoxides with arynes is reported. This reaction represents a rare instance of semipolar single bond insertion in aryne chemistry. The study of mechanism indicates that a sulfur ylide triggered by aryne is the key intermediate, which further transfers its methylene group to carbonyl compounds to give epoxides and ...
Hong-Ying, Li   +5 more
openaire   +2 more sources

The “Sulfoxide Bond”

Angewandte Chemie International Edition in English, 1972
H, Bock, B, Solouki
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Penicillin Sulfoxides

The Journal of Organic Chemistry, 1965
J M, Essery   +4 more
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Sulfoxides

1987
C R, Johnson, M P, Westrick
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