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Total Synthesis of Tetrodotoxin
Angewandte Chemie International Edition, 2020AbstractA total synthesis of tetrodotoxin was accomplished. A Diels–Alder reaction between a known enone and a siloxy diene gave a tricyclic product, the steric bias of which was used to construct the remaining stereogenic centers. A nitrogen atom was introduced either by a four‐step sequence involving a Curtius rearrangement, or a three‐step sequence ...
Keigo Murakami +3 more
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Tetrodotoxin and neuromuscular transmission
Proceedings of the Royal Society of London. Series B. Biological Sciences, 19671. The puffer fish poison, tetrodotoxin ( T . T .) was applied to eliminate impulse propagation in nerve and muscle fibre, and the physiological properties of the neuromuscular junction were studied under this condition. 2.
B, Katz, R, Miledi
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Tetrodotoxin-resistant sodium channels
Cellular and Molecular Neurobiology, 19941. Tetrodotoxin (TTX) has been widely used as a chemical tool for blocking Na+ channels. However, reports are accumulating that some Na+ channels are resistant to TTX in various tissues and in different animal species. Studying the sensitivity of Na+ channels to TTX may provide us with an insight into the evolution of Na+ channels. 2.
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