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A 1,2,3-thiadiazole–1,2,3-thiadiazole rearrangement

J. Chem. Soc., Chem. Commun., 1983
During its preparation, 4-ethoxycarbonyl-5-diazomethyl-1,2,3-thiadiazole (4), undergoes a ring transformation into the isomeric structure (5), but when the ester function in (4) is replaced by a phenyl group, no isomerization is observed.
Gerrit L'abbé   +2 more
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1,2,3‐Thiadiazoles

ChemInform, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
D. J. Wilkins, P. A. Bradley
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The 1,2,5-Thiadiazoles

1968
Publisher Summary This chapter presents the review of organic and physical chemistry of monocyclic 1, 2, 5-thiadiazoles up to the early part of 1967. Reference is made to the 2, 1, 3-benzothiadiazoles and related compounds only as they contribute to the chemistry of the basic ring system. The 1, 2, 5-thiadiazole nucleus is numbered as in 4.
L M, Weinstock, P I, Pollak
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Thiadiazoles

Heterocycles containing nitrogen, oxygen and sulfur have been under investigation for a long time because of their important medicinal properties. The literature survey has described that thiadiazole moieties serve as analgesic, anti-inflammatory, anti-microbial activities, antihypertensive,anticancer, antituberculosis and vasodilator and this ...
G. Nagendra   +3 more
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1,3,4‐Thiadiazoles

ChemInform, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
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Liquid crystalline thiadiazole derivatives: new ferroelectric thiadiazole derivatives

Liquid Crystals, 2002
A series of optically active thiadiazole Schiff's bases were prepared and their liquid crystalline properties were studied. Chirality was achieved by introducing an asymmetric carbon atom into the alkoxy group. Thus, 2-(p -active-alkoxyphenyl-imine)-5-(p-n-alkoxy)phenyl-1,3,4-thiadiazoles were synthesized.
Yan Xu   +5 more
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Alkynylated Aceno[2,1,3]thiadiazoles

Organic Letters, 2009
Enlarged acenothiadiazoles, which are easily prepared, display attractive optical and electrochemical properties. The annulation of thiadiazole to anthracene gives a stable material with optical properties similar to those of substituted pentacenes.
Anthony Lucas, Appleton   +8 more
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Thiadiazole-Derived Expanded Heteroazaporphyrinoids

Organic Letters, 2001
[structure: see text] Heteroannulenes 1 and 3 containing three subunits of isoindole or pyrrole, respectively, three 1,3,4-thiadiazole moieties, and six aza-bridges have been synthesized by reaction of the corresponding diiminoisoindoline or diiminopyrroline with 2,5-diamino-1,3,4-thiadiazole.
M K, Islyaikin   +4 more
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1,2,4-Thiadiazole

2015
[288-92-6] C2H2N2S (MW 86.11) InChI = 1S/C2H2N2S/c1-3-2-5-4-1/h1-2H InChIKey = YGTAZGSLCXNBQL-UHFFFAOYSA-N (prepared from 5-bromo-1,2,4-thiadiazole) Alternate Name(s): 1-thia-2,4-diazacyclopentadiene; 2,4-diazathiophene. Physical Data: mp −33 to −35 °C, bp753 120.7–121.2 °C, d 1.3298 g mL−1 at 20 °C, 1.5316; λmax 229 nm ...
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ChemInform Abstract: A 1,2,3‐THIADIAZOLE‐1,2,3‐THIADIAZOLE REARRANGEMENT

Chemischer Informationsdienst, 1983
AbstractAus den Thiadiazolen (I) und (IV) entstehen unter Umlagerung die Diazoverbindungen (II) bzw. (V).
G. L'ABBE, J.‐P. DEKERK, M. DEKETELE
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