Photokatalytische Erzeugung eines Elektronendonors im Grundzustand durch Wasseraktivierung
Diese Studie stellt katalytisch erzeugte Phosphanoxid‐Radikalanionen, die aus kommerziellen Phosphanen und Wasser als potente Einelektron‐Reduktionsmittel abgeleitet werden, die in der Lage sind, elektronenreiche Arylchloride bei Potentialen von bis zu ‐3,3 V (vs. SCE) zu reduzieren.
Maxim‐Aleksa Wiethoff+2 more
wiley +1 more source
Base‐Catalyzed Remote Hydrogermylation of Olefins
This study presents the first remote hydrogermylation of alkenes, utilizing a rare base‐catalyzed strategy in the absence of transition metal catalysts. The methodology is operationally simple and highly versatile, enabling up to 8‐carbon chain walks.
Eric Ahrweiler+2 more
wiley +2 more sources
New thiophene derivatives: chemoselective synthesis, antitumor effectiveness, structural characterization, DFT calculations, Hirshfeld surface, and Fukui function analysis. [PDF]
Bin Muhsinah A+7 more
europepmc +1 more source
A Highly Correlated, Multireference Study of the Lowest Lying Singlet and Triplet States of the Four Thiophene Diradicals. [PDF]
Pandian J+7 more
europepmc +1 more source
Benzo[b]thiophene derivatives. XV. preparation and electrophilic substitution of 6‐methoxy‐3‐methylbenzo[b] thiophene [PDF]
E. Campaigne, A. DINNER, E. S. Neiss
openalex +1 more source
The synthesis and catalytic properties of Ni(II) complexes, with the general formula Ni(NHC)[P(OR)3](Ar)Cl, are described. These air‐stable complexes are effective under mild conditions and low catalytic loading for the Suzuki‐Miyaura cross‐coupling for a range of electronically and sterically differentiated coupling partners.
Morgan E. John+9 more
wiley +2 more sources
Synthesis of bicyclo[3.2.0]heptane lactones <i>via</i> a ligand-enabled Pd-catalyzed C(sp<sup>3</sup>)-H activation cascade. [PDF]
Fan Z, Cai X, Sheng T, Yu JQ.
europepmc +1 more source
Alternative Approach to Sequence-Specific Recognition of DNA: Cooperative Stacking of Dication Dimers─Sensitivity to Compound Curvature, Aromatic Structure, and DNA Sequence. [PDF]
Paul A+7 more
europepmc +1 more source
Bioinspirierte Kationische Antimikrobielle Polymere
Dieser Übersichtsartikel behandelt Membran‐aktive kationische Polymere mit antimikrobiellen Eigenschaften. Im Fokus stehen Aspekte wie die Polymerarchitektur, Stimuli‐responsive antimikrobielle Polymere sowie Synergien von Polymeren und anderen Verbindungen.
Heliya Javadi+2 more
wiley +1 more source
Expanding the Molecular Switches Toolbox: Photoreloadable Dithienylethene Mechanophores. [PDF]
Steponavičiūtė M+4 more
europepmc +1 more source