Results 271 to 280 of about 39,833 (328)

Long-chain alkanes preserved in a Martian mudstone. [PDF]

open access: yesProc Natl Acad Sci U S A
Freissinet C   +21 more
europepmc   +1 more source

Photoinduced Boron‐Catalyzed Direct α‐Aminoxylation of Carboxylic Acids

open access: yesChemistryEurope, EarlyView.
A boron‐catalyzed α‐aminoxylation of carboxylic acids enables rapid access to sterically congested α‐(aminoxy)carboxylic acids. Photoexcited diboron enediolates transfer energy to O‐sulfonylhydroxylamines, triggering SO bond cleavage to generate N‐oxyl radicals.
Tsubasa Oyama   +5 more
wiley   +1 more source

One‐Pot Ruthenium‐Catalyzed Synthesis of Benzyl/Allyl‐Halide Substituted (dihydro)naphthalenes via Radical Benzannulation

open access: yesChemistryEurope, EarlyView.
A one‐pot protocol to synthesize reactive benzyl‐ and allyl‐halide‐substituted (dihydro)naphthalenes from 2,3‐aryl‐1,3‐butadiene substrates and halogenated alkanes has been developed, using [Cp*RuCl(PPh3)2] as the catalyst. Mechanistic studies revealed an atom transfer radical addition and radical benzannulation sequence, followed by HCl elimination ...
Nicole S. van Leeuwen   +9 more
wiley   +1 more source

Pollutants Transformation During the Regeneration Process of Fluid Catalytic Cracking Catalysts. [PDF]

open access: yesAngew Chem Int Ed Engl
Bian J   +8 more
europepmc   +1 more source

Introducing the Cis‐2,3‐Bis(trifluoromethyl)cyclopropyl Chemotype: Late‐Stage Installation and Stereoelectronic Properties

open access: yesChemistryEurope, EarlyView.
The cis‐2,3‐bis(trifluoromethyl)cyclopropyl chemotype is introduced. The steric demand of this motif is intermediate between that of the heptafluoroisopropyl and prefluorotertbutyl groups; yet, it induces significantly less lipophilicity than these due to its facial polarity.
Daniel Gaviña   +5 more
wiley   +1 more source

Tailored Core-Shell Nanocarrier for Therapeutic Drug Delivery via Visible Light Activation. [PDF]

open access: yesAngew Chem Int Ed Engl
Andrade-Alarcón D   +3 more
europepmc   +1 more source

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