Results 61 to 70 of about 36,445 (329)
Novel conjugated polymers with side‐chain π‐conjugation are developed to enhance organic thermoelectric properties. Remarkably, the pendant doping in the conjugated polymers preserved strong intermolecular ordering in the film states even at high FeCl3 dopant concentrations (16 – 32 mM), achieving a promising power factor > 10 µW m−1 K−2 across a wide ...
Hyeokjun Kim+4 more
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Recent Advances in the Synthesis of Thiophene Derivatives by Cyclization of Functionalized Alkynes
This review is intended to highlight some recent and particularly interesting examples of the synthesis of thiophene derivatives by heterocyclization of readily available S-containing alkyne substrates.
Raffaella Mancuso, Bartolo Gabriele
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Resumen de la comunicaciónDiradicals are defined as molecules with two unpaired electrons which define distinctive manifolds of singlet and triplet states.
Casado-Cordon, Juan
core
Synthesis of Fused Furans and Thiophenes via Ruthenium-Catalyzed Atom-Transfer [2+2+1] Cycloadditions of α,ω-Diynes [PDF]
Furans and thiophenes are important five-membered heterocyclic compounds that are found in natural products, functional materials, and pharmaceutics. This account outlines our studies on ruthenium-catalyzed atom-transfer [2+2+1] cycloadditions toward the
73610, Yamamoto, Yoshihiko
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An asymmetric non‐fullerene acceptor BTP‐FT is developed by extending the end group of Y6‐BO with thiophene. The conformation of the molecule is determined by the noncovalent F···S interaction as demonstrated by 2D NMR and simulations. An efficiency of 18.39% is achieved in the resulting ternary solar cells processed from toluene.
Jingnan Wu+14 more
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In this manuscript, we report clear evidence for the generation of aromatic cation radicals produced by using [hydroxy(tosyloxy)iodo]benzene (HTIB) in fluoroalcohol solvents such as 2,2,2-trifluoroethanol (TFE) and 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP)
Toshifumi Dohi+5 more
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Influence of solvent and substituents on the reaction of N-alkylthioacetamides with dimethyl acetylenedicarboxylate: Synthesis of functionalized thiophenes containing an exocyclic double bond [PDF]
The reaction of thioacetamides with dimethyl acetylenedicarboxylate affords 3-oxothien-2-ylidene or 4-oxothiazol-2,5-ylidene derivatives based on the structure of the thioacetamides and the solvent employed.
Klimareva, E. L.+4 more
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Rigid Fluorescent Indacenetetraone‐Based Semiconducting Polymers via Knoevenagel Condensation
New donor–acceptor polymers prepared by Knoevenagel condensation of indacenedithiophene‐ and indacenedifuran‐based aldehydes reveal an exceptionally rigid backbone, which is manifested in the remarkably narrow absorption and emission bands in red to near‐infrared region.
So‐Huei Kang+7 more
wiley +1 more source
A new approach towards the synthesis of multisubstituted thiophenes is elaborated based on Rh(II)-catalyzed domino reactions of acyclic diazoesters with α-cyanothioacetamides.
Jury J. Medvedev+5 more
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Catalytic asymmetric dearomatization is a powerful tool for the rapid construction of diverse chiral cyclic molecules from cheap and easily available arenes.
Xingguang Li+4 more
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