Results 71 to 80 of about 36,445 (329)

One-Pot Synthesis of 2-(Aryl/Alkyl)amino-3-cyanobenzobthiophenes and Their Hetero-Fused Analogues by Pd-Catalyzed Intramolecular Oxidative C�H Functionalization/Arylthiolation [PDF]

, 2017
We have developed a high-yielding synthesis for substituted 2-(aryl/alkyl)amino-3-cyanobenzobthiophenes and their hetero-fused analogues by using a palladium-catalyzed intramolecular oxidative Câ H functionalization/arylthiolation reaction of in situ ...
Acharya, A., Gautam, V., Hiriyakkanavar, I., Pasha, M.A., Saraiah, B.   +4 more
core   +1 more source

The “simple” photochemistry of thiophene

The Journal of Chemical Physics
The static gas-phase (“simple”) ultraviolet absorption spectrum of thiophene is investigated using a combination of a vibronic coupling model Hamiltonian with multi-configuration time-dependent Hartree quantum dynamics simulations. The model includes five states and all 21 vibrations, with potential surfaces calculated at the complete active space with
Michael A. Parkes, Graham A. Worth
openaire   +3 more sources

Light‐Mediated Photomultiplication via Cascade Energy Transfer in Organic Photodiode

Advanced Functional Materials, EarlyView.
Light‐mediated photomultiplication via cascade energy transfer in organic photodiode demonstrates external quantum efficiency exceeding 200% and specific detectivity surpassing 5.0 × 1013 Jones. This advancement effectively addresses the limitation of elevated dark current density characteristic of prior photomultiplication organic photodetectors ...
Gae Hwang Lee, Jae‐Hyun Kim, Hyunbum Kang, Jaebin Jeong, Jong Won Chung, Dongwook Kim, Jaehoon Park, Youngjun Yun, Sungjun Park   +8 more
wiley   +1 more source

Organic-skinned inorganic nanoparticles: surface-confined polymerization of 6-(3-thienyl)hexanoic acid bound to nanocrystalline TiO₂

Nanoscale Research Letters, 2011
There are many practical difficulties in direct adsorption of polymers onto nanocrystalline inorganic oxide surface such as Al2O3 and TiO2 mainly due to the insolubility of polymers in solvents or polymer agglomeration during adsorption process.
Saji Viswanathan, Jo Yimhyun, Moon Hoi, Jun Yongseok, Song Hyun-Kon   +4 more
doaj  

Mechanistic Study of Pd/Ag Dual-Catalyzed Cross-Dehydrogenative Coupling of Perfluoroarenes with Thiophenes [PDF]

, 2020
The mechanism of the Pd/Ag dual-catalyzed cross-dehydrogenative coupling (CDC) between perfluoroarenes and thiophenes was clarified. The exact role of the catalytic resting state of the homo-biaryl-Pd(II) complex which was previously overlooked in Pd/Ag ...
0000000760, 0000000761, KANBARA Takaki, KUWABARA Junpei, Shimoyama Yuto   +4 more
core   +1 more source

Ferrocene Derivatives Enable Ultrasensitive Perovskite Photodetectors with Enhanced Reverse Bias Stability

Advanced Functional Materials, EarlyView.
Novel ferrocene derivatives (e.g., FcPhc2) are used as an ultrathin layer hole‐blocking layer, reducing hole injection from the Ag contact. This results in an ultralow noise spectral density of 1.2 × 10−14 A Hz−1/2, and a high specific detectivity of 8.1 × 1012 Jones at −0.5 V.
Eunyoung Hong, William D. J. Tremlett, Lucy Hart, Beier Hu, Zhuoran Qiao, Patipan Sukpoonprom, Sarah Fearn, Edoardo Angela, Matilde Brunetta, Demosthenes C. Koutsogeorgis, Nikolaos Kalfagiannis, Davide Nodari, Martyn A. McLachlan, Piers R. F. Barnes, Artem A. Bakulin, Nicholas J. Long, Nicola Gasparini   +16 more
wiley   +1 more source

Hindered aryl bromides for regioselective palladium-catalysed direct arylation at less favourable C5-carbon of 3-substituted thiophenes

Beilstein Journal of Organic Chemistry, 2014
The use of the congested aryl bromide 2-bromo-1,3-dichlorobenzene as coupling partner allows to modify the regioselectivity of the arylation of 3-substituted thiophene derivatives in favour of carbon C5.
Rongwei Jin, Charles Beromeo Bheeter, Henri Doucet   +2 more
doaj   +1 more source

Solution‐Processable and Ambient‐Stable Highly Conductive p‐Type Polymers Derived from Dihydropyrazine and Ethylenedioxythiophene

Advanced Functional Materials, EarlyView.
This work presents π–conjugated polymers based on dihydropyrazine (DHP) and ethylenedioxythiophene (EDOT), developed to produce highly conductive, flexible films for printed electronics. By optimizing the DHP and EDOT ratio, strong and compact π–π stacking is achieved, resulting in polymer films with conductivities up to 1700 S cm−1 under ambient ...
Sung Jae Jeon, Naixin Zhao, Yi Yuan, Yuning Li   +3 more
wiley   +1 more source

It Matters Where the Heavy Atom Is Placed: Optimizing the Spin–Orbital Coupling in Multiresonant TADF (MR‐TADF) Emitters and Its Impact on OLED Performance

Advanced Functional Materials, EarlyView.
The TOC showcases the chemical structure of the emitter tCzBT2B as an “MVP athlete” in a stadium surrounded by. spotlights and cheering fans celebrating its impressive performance in organic light‐emitting diodes (OLEDs). The stats for this emitter and its device are detailed below.
Dongyang Chen, Hui Wang, Feng Huang, David B. Cordes, Aidan P. McKay, Kai Wang, Xiao‐Hong Zhang, Eli Zysman‐Colman   +7 more
wiley   +1 more source

Organic indicators of alteration in the CR chondrites [PDF]

, 2002
A study of the organic components in the CR chondrite macromolecule in order to assess the role of pre-terrestrial alteration on the organic ...
Gilmour, I., Pearson, V. K., Sephton, M. A.   +2 more
core