Results 11 to 20 of about 28,818 (311)

Beyond Chiral Organic (p-Block) Chromophores for Circularly Polarized Luminescence: The Success of d-Block and f-Block Chiral Complexes

open access: yesFrontiers in Chemistry, 2020
Chiral molecules are essential for the development of advanced technological applications in spintronic and photonic. The best systems should produce large circularly polarized luminescence (CPL) as estimated by their dissymmetry factor (glum), which can
Benjamin Doistau   +2 more
doaj   +1 more source

Photoactivation of trans diamine platinum complexes in aqueous solution and effect on reactivity towards nucleotides [PDF]

open access: yes, 2010
We show that UVA irradiation (365 nm) of the Pt-IV complex trans,trans,trans-[(PtCl2)-Cl-IV(OH)(2)(dimethylamine) (isopropylamine)] (1), induces reduction to Pt-II photoproducts.
Pizarro, Ana M.   +5 more
core   +1 more source

Synthesis, characterisation and photochemistry of PtIV pyridyl azido acetato complexes [PDF]

open access: yes, 2009
PtII azido complexes [Pt(bpy)(N3)2] (1), [Pt(phen)(N3)2] (2) and trans-[Pt(N3)2(py)2] (3) incorporating the bidentate diimine ligands 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen) or the monodentate pyridine (py) respectively, have been synthesised ...
Wood, Peter A.   +11 more
core   +1 more source

Fundamental Studies of Early Transition Metal-Ligand Multiple Bonds: Structure, Electronics, and Catalysis [PDF]

open access: yes, 2011
Two major topics are covered: the first section is focused on the structure, electronics, stoichiometric reactivity and catalysis of nonmetallocene early transition metal complexes that often contain metal-ligand multiple bonds (Chapters 2-4); the second
Ian Albert Tonks, Tonks, Ian Albert
core   +1 more source

Critical roles of metal–ligand complexes in the controlled synthesis of various metal nanoclusters

open access: yesNature Communications, 2023
Metal nanoclusters (NCs), an important class of nanoparticles (NPs), are extremely small in size and possess quasi-molecular properties. Due to accurate stoichiometry of constituent atoms and ligands, NCs have strong structure-property relationship.
Ji Soo Kim   +14 more
doaj   +1 more source

Electronic Structure of Metal Ion-Dioxygen Complexes [PDF]

open access: yes, 1973
The electronic structures of cobalt complexes containing O2 units as ligands have been investigated, primarily by electronic spectroscopy. Various cobalt complexes containing, the structural units present in the O2 complexes were investigated, and a ...
Miskowski, Vincent Mark
core   +1 more source

Synthesis , Characterization , Antimicrobial New 2,2'-[(1E,2E)-ethane-1,2-diylidenedi(2E)hydrazin-1-yl-2-ylidene]bis (5-methyl-1,3,4-oxadiazole) and their transition metal complexes

open access: yesمجلة علوم ذي قار, 2019
        Transition metal complexes of new legend 2,2'-[(1E,2E)-ethane-1,2-diylidenedi(2E) hydrazin-1-yl-2-ylidene] bis (5-methyl-1,3,4-oxadiazole) with some transition metal ion such as Cr3, Co3+, Ni2+  were synthesis ,characterization by magnetic ...
Azhar H. Katea
doaj   +4 more sources

Mammea A/AA (MA) potency as ratiometric absorbance based molecular probe: Cations detection and quantification ability

open access: yesResults in Chemistry, 2023
MA is a phenyl coumarin extracted from the bark of the stem of Mammea Africana. This compound exhibits two absorption peaks in the region between 300 and 550 nm, whose relative wavelength positions, their absolute absorbances and the ratio of their ...
Mathieu Jules Mbenga Tjegbe   +3 more
doaj   +1 more source

Cooperativity in Transition Metal Tetrylene Complexes [PDF]

open access: yesEuropean Journal of Inorganic Chemistry, 2021
AbstractCooperative reactivity between transition metals and ligands, or between two metals, has created significant opportunities for the development of new transformations that would be difficult to carry out with a single metal. Here we explore cooperativity between transition metals and divalent heavier group 14 elements (tetrylenes), a less ...
Rosie J. Somerville, Jesús Campos
openaire   +3 more sources

Structural, Spectroscopic, and Bonding Analyses of La(III)/Ce(III)-Tetrel Ate-Complexes

open access: yes, 2023
In comparison with the research of transition-metal-tetrel complexes, the chemistry of lanthanide tetrel complexes, especially for these bearing heavier tetrel element ligands, is still relatively underexplored.
Changjiang Wu (6059348)   +3 more
core   +2 more sources

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