Results 31 to 40 of about 28,818 (311)
Protein pyrophosphorylation by inositol pyrophosphates — detection, function, and regulation
Protein pyrophosphorylation is an unusual signaling mechanism that was discovered two decades ago. It can be driven by inositol pyrophosphate messengers and influences various cellular processes. Herein, we summarize the research progress and challenges of this field, covering pathways found to be regulated by this posttranslational modification as ...
Sarah Lampe +3 more
wiley +1 more source
Acetohydroxamatoiron(III) complexes : thermodynamics of formation and temperature dependent speciation. [PDF]
Studies of the thermodynamics of formation of the acetohydroxamatoiron(III) complexes were carried out in acidic media at temperatures ranging from 293 to 323 K.
Boxall, Colin +2 more
core
We study the optical properties of Agn (n = 3–12) neutral clusters and their coordination with a tyrosine (Tyr) molecule. A global search strategy coupled with density functional theory (DFT) computations explored the potential energy surface. Adsorption
José Luis Balan +4 more
doaj +1 more source
We reconstituted Synechocystis glycogen synthesis in vitro from purified enzymes and showed that two GlgA isoenzymes produce glycogen with different architectures: GlgA1 yields denser, highly branched glycogen, whereas GlgA2 synthesizes longer, less‐branched chains.
Kenric Lee +3 more
wiley +1 more source
Electronic Structure, IR and UV-Vis Spectra of Some Suggested Ziegler-Natta Catalysts
Three aluminum metal complexes were suggested as Ziegler-Natta catalysts and studied theoretically at the ground and excited states. Becke’s three parameter exchange with Lee, Yang, and Parr correlation functional) density functional theory and SDD ...
Faeq A. AL-Temimeia, Hamid I. Abboodb
doaj +1 more source
Metal-metal bond lengths in complexes of transition metals [PDF]
In complexes of the transition metals containing clusters of metal atoms the cobalt-cobalt bond lengths are almost always within 1 pm of the single-bond value 246 pm given by the enneacovalent radius of cobalt, whereas most of the observed iron-iron bond lengths are significantly larger than the single-bond value 248 pm, the mean being 264
openaire +2 more sources
Calpain small subunit homodimerization is robust and calcium‐independent
Calpains dimerize via penta‐EF‐hand (PEF) domains. Using single‐molecule force spectroscopy, we measured the strength and kinetics of PEF–PEF homodimer binding. The interaction is robust, shows a transient conformational step before dissociation, and remains largely insensitive to Ca2+.
Nesha May O. Andoy +4 more
wiley +1 more source
Charge-Transfer Processes in Metal Complexes Enable Luminescence and Memory Functions
Molecular transition-metal–ligand complexes are emerging as useful paradigms in materials science. Transition metal complexes have diverse metal d electron configurations, oxidation states, coordination numbers and geometries such that they can undergo a
Chan, AKW, Yam, VWW, Hong, EYH
core +1 more source
Spectroscopic characterization of chloride and pseudohalide ruthenium(II) complexes with 4-(4-nitrobenzyl)pyridine [PDF]
Chloride, isocyanate and isothiocyanate hydride carbonyl ruthenium(II) complexes of 4-(4-nitrobenzyl)pyridine were synthesized from the precursor complex [RuHCl(CO)(PPh3)3] and characterized by IR, NMR, UV-Vis spectroscopy and X-ray crystallography.
Jan G. Małecki +3 more
core +1 more source
Structural insights into an engineered feruloyl esterase with improved MHET degrading properties
A feruloyl esterase was engineered to mimic key features of MHETase, enhancing the degradation of PET oligomers. Structural and computational analysis reveal how a point mutation stabilizes the active site and reshapes the binding cleft, expading substrate scope.
Panagiota Karampa +5 more
wiley +1 more source

