Results 21 to 30 of about 28,818 (311)
New mononuclear ternary transition metal complexes: [M(HL)(bipy)2]ClO4, (M: Mn(II) for 1, Ni(II) for 2), [M(HL)(bipy) (ClO4)], (M: Ni(II) for 3, Cu(II) for 4, Zn(II) for 5) with M(II), 2-[(E)-(hydroxyimino)methyl]-4-[(E)-phenyldiazenyl]phenol, H2L, and 2,
Kerim Serbest +5 more
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Cooperative Spin Transitions Triggered by Phonons in Metal Complexes Coupled to Molecular Vibrations
The present article is a short overview of the theoretical modeling of spin transitions in polymetallic compounds. As distinguished from many insightful reviews on this topic, the present work is focused on the nature of cooperative interaction of the ...
Sophia Klokishner +3 more
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Transition-Metal Complexes of Expanded Porphyrins [PDF]
Over the last 2 decades, the rapid development of new synthetic routes for the preparation of expanded porphyrin macrocycles has allowed for the exploration of a new frontier consisting of "porphyrin-like" coordination chemistry. In this Account, we summarize our exploratory forays into the still relatively poorly explored area of oligopyrrolic ...
Jonathan L, Sessler, Elisa, Tomat
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Important applications of the NiII, PdII and PtII complexes [M(Hdmg)2] (H2dmg = dimethylglyoxime) stem from their metal...metal stacked virtually insoluble aggregates.
Maryam Niazi, Axel Klein
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Transition Metal Boryl Complexes
The article represents a review of the chemistry of transition metal complexes containing the boryl (–BX2) ligand based on the chemical literature published up to and including the calendar year 2006. A brief compendium of papers published in the year 2007 is also included.
Kays, D, Aldridge, S
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Optical and surface properties of Schiff base ligands and Cu(II) and Co(II) complexes
Objectives. To study the transition of electrons in 1,2-phenyl(4’-carboxy)benzylidene Schiff base ligand and transition metal ions, optical properties, as well as the surface chemistry of supported transition metals using diffuse reflectance spectroscopy
Alaa Adnan Rashad +6 more
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Preparation and characterization of novel oxo-centered basic p-chlorobenzoic bridging trinuclear complexes [PDF]
Three new oxo-centered trinuclear complexes, one of them a mixed-valence complex [Mn3O(C7H4O2Cl)6(Py)3]Py (1) and the others, mixed-metal complexes of [Fe2MnO(C7H4O2Cl)6(Py)3]NO3 (2) and [Fe2CoO(C7H4O2Cl)6(Py)3] (3) were synthesized by the direct ...
MOHAMMAD YAZDANBAKHSH, IMAN KHOSRAVI
doaj
New mononuclear platinum(IV) and dinuclear ruthenium(III) complexes were synthesized with the o-phenylenediamine (OPD) ligand. The complexes were characterized by different spectroscopic techniques, and DFT calculations and their cytotoxic activity has ...
Othman I. Alajrawy +3 more
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Gold Nanoclusters: Bridging Gold Complexes and Plasmonic Nanoparticles in Photophysical Properties
Recent advances in the determination of crystal structures and studies of optical properties of gold nanoclusters in the size range from tens to hundreds of gold atoms have started to reveal the grand evolution from gold complexes to nanoclusters and ...
Meng Zhou +4 more
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Synthesis and X-ray Structures of Potential Light-Harvesting Ruthenium(II) Complexes
We synthesized the luminescent ruthenium(II) polypyridyl complexes of type [Ru(bpy)2(L1)][ClO4]2 (1) (where L1 = 4,4-dicarboxy-2,2-bipyridine); [Ru(bpy)2(L2)][ClO4]2 (2); and [Ru(L2)3][ClO4]2 (3) (where L2 = 4,4-dimethanol-2,2-bipyridine). Photo-physical
Kadarkaraisamy Mariappan +6 more
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