Decarboxylative trifluoromethylthiolation of pyridylacetates [PDF]
Beilstein Journal of Organic Chemistry, 2021 Decarboxylative trifluoromethylthiolation of lithium pyridylacetates was achieved using N-(trifluoromethylthio)benzenesulfonimide as the electrophilic trifluoromethylthiolation reagent.
Ryouta Kawanishi +2 more
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C–H Trifluoromethylthiolation of aldehyde hydrazones [PDF]
Beilstein Journal of Organic ChemistryThe selective C–H trifluoromethylthiolation of aldehyde hydrazones afforded interesting fluorinated building blocks, which could be used as a synthetic platform.
Victor Levet +3 more
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Selenide-catalyzed enantioselective synthesis of trifluoromethylthiolated tetrahydronaphthalenes by merging desymmetrization and trifluoromethylthiolation [PDF]
Nature Communications, 2018 Catalytic enantioselective synthesis of trifluoromethylthiolated molecules remains a challenge. Here, the authors report a bifunctional selenide-catalyzed approach for the synthesis of structurally complex chiral trifluoromethylthiolated ...
Jie Luo +3 more
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Cascade trifluoromethylthiolation and cyclization of N-[(3-aryl)propioloyl]indoles [PDF]
Beilstein Journal of Organic Chemistry, 2020 A cascade oxidative trifluoromethylthiolation and cyclization of N-[(3-aryl)propioloyl]indoles with AgSCF3 is described. This protocol allows for the synthesis of novel bis(trifluoromethylthiolated) or trifluoromethylthiolated pyrrolo[1,2-a]indol-3-ones ...
Ming-Xi Bi +4 more
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Direct electrophilic N-trifluoromethylthiolation of amines with trifluoromethanesulfenamide
Beilstein Journal of Organic Chemistry, 2013 The CF3SN moiety is a substituent with interesting properties. However, there is no easy synthetic access to molecules bearing this group. The trifluoromethanesulfenamide is a new reagent for the electrophilic trifluoromethylthiolation which reacts ...
Thierry Billard, Sébastien Alazet
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Sulfonamide-directed site-selective functionalization of unactivated C(sp3)−H enabled by photocatalytic sequential electron/proton transfer [PDF]
Nature CommunicationsThe generation of alkyl radical from C(sp3)−H substrates via hydrogen atom abstraction represents a desirable yet underexplored strategy in alkylation reaction since involving common concerns remain adequately unaddressed, such as the harsh reaction ...
Chaodong Wang +6 more
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Gold (I/III)-Catalyzed Trifluoromethylthiolation and Trifluoromethylselenolation of Organohalides [PDF]
Angewandte Chemie - International Edition, 2022 Bo Xu, Zhichao Lu, Gerald B Hammond
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Trifluoromethyl Sulfoxides: Reagents for Metal-Free C−H Trifluoromethylthiolation [PDF]
Angewandte Chemie - International Edition, 2020 Joseph McDouall +2 more
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Transition-metal-free trifluoromethylthiolation–acylation of arynes by insertion into the C–S bonds
Green Synthesis and Catalysis, 2021 An efficient procedure to access to ortho-SCF3 substituted benzophenones from arynes and trifluoromethylthioesters has been developed under transition-metal free conditions. This difunctionalization process involves the first insertion of arynes into the
Chengyao Kimmy Cao +2 more
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Metal-free visible-light-enabled vicinal trifluoromethyl dithiolation of unactivated alkenes
Beilstein Journal of Organic Chemistry, 2021 The difunctionalization of alkenes involving a trifluoromethylthio group (SCF3) for the conversion of versatile and readily available olefins into structurally more complex molecules has been successfully studied.
Xiaojuan Li +5 more
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