Results 31 to 40 of about 2,928 (218)
Keggin-Type Heteropolyacids-Catalyzed One Pot Oxidation-Trimerization of Alcohols into 2,4,6-Trisubstituted-1,3,5-Trioxanes [PDF]
The catalytic air oxidation-trimerization of alcohols was carried out with hetropolyacids. In the presence of hetropolyacid formation of cyclotrimers of alcohols and aldol condensation products was observed.
M. Majid Heravi +4 more
doaj
A protocol based on photocatalytic cycles of both iron(III)chloride and 9,10-dicyanoanthracene (DCA) is developed for the masked hydroformylation, hydroacylation, and hydrocarboxylation of Michael-Acceptors utilizing readily available 1,3,5-trioxanes ...
Viktor Klöpfer +2 more
doaj +1 more source
A kinetic and mechanistic study on the thermal decomposition reactions of cis- and trans- fused 1,2,4-trioxanes [PDF]
The kinetics of the thermal decomposition reactions of artemisinine (1), a cis-fused 1,2,4-trioxane, and trans-3,3dimethyl-1,2,4-trioxane (6) in solutions of benzene, toluene, and methanol in sealed tubes were compared at temperatures between 100.1° and ...
Cafferata, Lázaro F. R. +4 more
core +2 more sources
Antimalarial sulfide, sulfone, and sulfonamide trioxanes
A series of trioxanes featuring sulfide, sulfone, and sulfonamide substituents in diverse positions has been prepared. Structure-activity relationship (SAR) generalizations highlight two major factors controlling the antimalarial potency of these new chemical entities: (1) the proximity of the sulfur-containing substituent to the crucial peroxide bond ...
G H, Posner +5 more
openaire +2 more sources
Structure–activity relationships of the antimalarial agent artemisinin 10. Synthesis and antimalarial activity of enantiomers of rac-5β-hydroxy-d-secoartemisinin and analogs: Implications regarding the mechanism of action [PDF]
An efficient synthesis of rac-6-desmethyl-5β–hydroxy-D-secoartemisinin 2, a tricyclic analog of R-(+)-artemisinin 1, was accomplished and the racemate was resolved into the (+)-2b and (−)-2a enantiomers via their Mosher Ester diastereomers.
Elokely, Khaled M. +3 more
core +2 more sources
Cinètica de la reacció de descomposició tèrmica de l’ascaridol en dissolució [PDF]
Existen diferencias entre los valores de algunas propiedades físicas de ascaridol natural aislado del vegetal denominado vulgarmente «Paico» (Chenopodium ambrosioides L., Chenopodiaceae) y la sustancia sintética obtenida mediante la reacción de ...
Cafferata, Lazaro +2 more
core +1 more source
Surface‐functionalized gold nanoclusters (AuNCs) are synthesized in situ by chain‐end grafting of RAFT polyelectrolytes at room temperature directly in water. It leads to highly stable polymer‐AuNCs nanohybrids emitting near‐infrared photoluminescence with µs lifetimes. ABSTRACT With their photoluminescence properties, gold nanoclusters (AuNCs, d<2 nm)
Bárbara Casteleiro +7 more
wiley +1 more source
ABSTRACT This study investigated the prevalence of electronic smoking device (ESD) use and its associated behavioural and chemical risks among university students in Bahia, Brazil. A cross‐sectional survey was conducted with 355 students from public and private institutions through an online questionnaire between April and May 2023. Among participants,
Eduard F. Valenzuela +7 more
wiley +1 more source
Artemisinin: From Chinese Herbal Medicine to Modern Chemotherapy [PDF]
Malaria is a disease that has blighted humankind since early times. The first antimalarial treatment available to Europeans was the dried bark of the cinchona tree from Peru. The main problem in its use was adulteration by other material.
Butler, Anthony
core +1 more source
Fluoro‐functionalized polyether electrolytes, which combine fluorine‐ and ether‐containing groups, achieve enhanced oxidative stability, high ionic conductivity, and superior interfacial stability. Due to their non‐flammability, remarkable flexibility, ease of processing, and design versatility, polymer‐based electrolytes containing polyethers have ...
Nannan Geng +8 more
wiley +1 more source

