Results 251 to 260 of about 62,631 (288)

Assessing the Mechanism of NH3 Sensing in Flexible Carbon‐Nanotube‐Based Chemoresistive Sensors via In Situ Photoemission Spectroscopy

open access: yesAdvanced Materials Interfaces, EarlyView.
Flexible carbon nanotube chemoresistors detect NH3 through charge‐transfer interactions directly revealed by in situ synchrotron X‐ray photoelectron spectroscopy. Binding‐energy shifts of ≈1 eV correlate with resistance changes, demonstrating that intra‐CNT charge transfer between NH3 and CNTs is the dominant sensing mechanism.
Christos Gatsios   +12 more
wiley   +1 more source

Laser‐Synthesized Amorphous PdSe2‐x Nanoparticles: A Defect‐Rich Platform for High‐Efficiency SERS, Photocatalysis, and Photothermal Conversion

open access: yesAdvanced Materials Interfaces, EarlyView.
Using femtosecond ablation, we show that an ordered, stoichiometric crystalline PdSe2 target can be controllably converted into a stable, disordered, non‐stoichiometric, and highly functional amorphous nanomaterial, PdSe2−x${\rm PdSe}_{2-x}$. The obtained nanoparticles offer significant advantages over conventional planar plasmon‐free substrates due to
Andrei Ushkov   +18 more
wiley   +1 more source

Investigating the Structural Factors Influencing the Magnetic Interaction between Individual Copper Spins in the CuCu4 Metallacrown Complex, from Its Bulk Form to Its Adsorption on Au(111)

open access: yesAdvanced Materials Interfaces, EarlyView.
The Cu(II)[12‐MCCu(II)N(Shi)‐4] metallacrown complex (CuCu4) is studied to examine how geometric transformations affect magnetic coupling between copper spins by using ultraviolet photoemission spectroscopy and DFT calculations for the bulk phase and CuCu4 adsorbed on Au(111). While adsorption minimally affects tDOS, exchange coupling constants between
Ariyan Tavakoli   +11 more
wiley   +1 more source

Powder‐to‐Film Conversion of Nickel Single‐Atom Catalysts into Binder‐Free and Resistant Electrodes

open access: yesAdvanced Materials Interfaces, EarlyView.
A reproducible strategy is reported for fabricating standalone thin‐film electrodes composed of CNx‐supported Ni single‐atom catalysts. The resulting binder‐free electrodes exhibit robust stability, enhanced charge transfer, and superior electrochemical performance, offering scalable opportunities for applications in electrochemistry. ABSTRACT Although
Milla Vigliengo   +8 more
wiley   +1 more source

Defect Properties and Band Energetics of Atomic Layer Deposited MoOX on Crystalline Si

open access: yesAdvanced Materials Interfaces, EarlyView.
Atomic layer deposited MoOx thin films grown using oxygen plasma and ozone co‐reactants exhibit tunable defect densities and band energetics. Optical and X#x02010;ray photoelectron spectroscopies reveal oxygen#x02010;vacancy#x02010;induced defect and polaron states and their impact on band alignment at the c#x02010;Si/MoOx interface, providing insight ...
Namitha Dsouza   +3 more
wiley   +1 more source

Defect‐Healed Au/rGO Coating for the Corrosion Protection of PEMFC Bipolar Plates

open access: yesAdvanced Materials Technologies, EarlyView.
 A defect‐healed gold/reduced graphene oxide (Au/rGO) coating is presented for stainless steel bipolar plates in polymer electrolyte membrane fuel cells. Gold nanoparticles nucleate at graphene oxide defects, blocking corrosive ion penetration and enhancing corrosion resistance, thereby ensuring durable fuel cell operation.
Jinmyeong Seo   +6 more
wiley   +1 more source

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