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Reaction of Bromine with Uracils

Nature, 1957
SOME interesting observations on the reaction of bromine with pyrimidine compounds were recently reported by Cohn1. Since 1907, when Wheeler and Johnson2 first observed the coloured reaction product obtained by the action of bromine with uracil or cytosine and isolated the intermediate, the bromine reaction has been utilized for structural ...
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Structures and Fragmentation of [Cu(Uracil‐H)(Uracil)]+ in the Gas Phase

ChemPhysChem, 2011
AbstractComplexes of copper (II) ions and uracil were studied using tandem mass spectrometry (Fourier transform ion cyclotron resonance, FTICR, mass spectrometry) including extensive isotopic labeling as well as theoretical calculations. Positive ion electrospray mass spectra of aqueous solutions of CuCl2 and uracil show that the [Cu(Ura‐H)(Ura)]+ ion ...
Osama Y. Ali, Travis D. Fridgen
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Protonation and deprotonation energies of uracil Implications for the uracil–water complex

Journal of the Chemical Society, Faraday Transactions, 1998
The proton affinities PA(B) of the four oxygen lone pairs and of the two nitrogen atoms and the deprotonation energies PA(A-) of the two NH bonds of uracil are calculated by density functional theory (DFT) using the 6-31G(d,p) and 6-31G++(d,p) basis set. The PAs are also calculated by abinitio MO theory (MP4) using 6-31G(d,p) for comparison.
Minh Tho Nguyen   +2 more
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DNA base stacking: The stacked uracil/uracil and thymine/thymine minima

Journal of Computational Chemistry, 2012
AbstractThe potential energy surfaces of stacked uracil dimer (U/U) and stacked thymine dimer (T/T) have been explored at the counterpoise (CP)‐corrected M06‐2X/6‐31+G(d) level of theory, in the gas phase and in solution (with water and, for U/U, 1,4‐dioxane as the solvents) modeled by a continuum solvent using the polarizable continuum model ...
Ruairidh S. Hunter, Tanja van Mourik
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ChemInform Abstract: Ozonolysis of Uracils in Water.

ChemInform, 1989
Abstract The ozonolysis of uracils unsubstituted at the 1-position gave new 1-acyl-5-hydroxyhydantoins and 5-hydroxyhydantoins in water, while that of 1-substituted uracils gave the corresponding 5-hydroxyhydantoins in low yields. The structure of 1-acetyl-5-hydroxy-5-methylhydantoin was determined by X-ray crystallography.
KamiyaKazusaki   +5 more
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Effect of certain uracil analogs on incorporation of uracil into RNA

Archives of Biochemistry and Biophysics, 1958
Karl E. Paschkis   +2 more
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THE MECHANISM OF PHOTOHYDRATION OF URACIL AND N‐SUBSTITUTED URACILS

Photochemistry and Photobiology, 1968
J. G. Burr, E. H. Park, B. R. Gordon
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The Direct Thiation of Uracils

Journal of the American Chemical Society, 1947
Gertrude B. Elion, George H. Hitchings
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