Results 61 to 70 of about 9,951 (268)

Real Time Observation of X-ray-Induced Surface Modification Using Simultaneous XANES and XEOL-XANES

Analytical Chemistry, 2013
In experiments preliminary to the design of an X-ray-excited optical luminescence (XEOL)-based chemical mapping tool we have used X-ray micro (4.5 × 5.2 μm) and macro (1 × 6 mm) beams with similar total fluxes to assess the effects of a high flux density beam of X-rays at energies close to an absorption edge on inorganic surfaces in air.
Adriaens A., Quinn P., Nikitenko S., Dowsett M.G.   +3 more
openaire   +3 more sources

The Influence of Mesoscale Particle Structure on the Electrode Degradation and Resultant Electrochemistry of Lithium Ion Cells With Nickel Rich Lithium Nickel Manganese Cobalt Oxide Positive Electrodes

Advanced Materials Technologies, EarlyView.
Milled polycrystalline NMC811 cathode (MPC NMC) with smaller secondary particle and higher surface area had 1) greater cathode tortuosity, 2) reduced surface Ni on the cycled MPC cathodes consistent with surface reconstruction, and 3) increased Ni deposition from cathode‐anode crosstalk, manifesting in lower functional capacity and higher impedance ...
Edelmy J. Marin Bernardez, Andrew Nicoll, David J. Arnot, Armando Rodriguez Campos, Patrick J. Barry, Marie F. Millares, Cynthia Huang, Melissa A. Guercio, Grace K. Dono, Alexis Pace, Xianghui Xiao, Cherno Jaye, Conan Weiland, Jianming Bai, Hui Zhong, Michael Drakopoulos, Zhong Zhong, Nghia T. Vo, Xiao Tong, Esther S. Takeuchi, Amy C. Marschilok, Shan Yan, Kenneth J. Takeuchi   +22 more
wiley   +1 more source

Synthesis and characterization of nanocrystalline U1-xPuxO2(+y) mixed oxides

Materials Today Advances, 2020
We report here the first synthesis of mixed oxide U1-xPuxO2(+y) nanoparticles. The obtained nanopowders were characterized by X-ray diffraction, thermal ionization mass spectrometry, transmission electron microscopy, Raman spectroscopy, and U M4 edge ...
G. Kauric, O. Walter, A. Beck, B. Schacherl, O. Dieste Blanco, J.-F. Vigier, E. Zuleger, T. Vitova, K. Popa   +8 more
doaj   +1 more source

Atomic Tuning of Metal‐Support Interactions for Pathway‐Selective CO2 Photoreduction on TiO2

Advanced Science, EarlyView.
Single‐atom Fe and Cu catalysts anchored on TiO2 steer photocatalytic CO2 reduction toward distinct pathways. Fe sites favor rapid *CO desorption and selective CO formation, whereas Cu sites stabilize *CHO intermediates, enabling deep reduction and C─C coupling. Combined spectroscopy and DFT calculations reveal how metal–support interactions and oxygen
Dongyun Kim, Wonjae Ko, Byoung‐Hoon Lee, Sanghoon Kim, Yun Do Kim, Hyunsoo Ahn, Yoon Jung, Chan Woo Lee, Kug‐Seung Lee, Eunhee Gong, Junho Lee, Minho Kim, Taeghwan Hyeon, Su‐Il In   +13 more
wiley   +1 more source

In situ photodeposition of ultra-small palladium particles on TiO2

Journal of Synchrotron Radiation
In situ and operando investigation of photocatalysts plays a fundamental role in understanding the processes of active phase formation and the mechanisms of catalytic reactions, which is crucial for the rational design of more efficient materials.
Elizaveta Kozyr, Sara Martí-Sánchez, Alina Skorynina, Jordi Arbiol, Carlos Escudero, Lorenzo Mino, Aram Bugaev   +6 more
doaj   +1 more source

Stage‐Adaptive Janus Microneedle System for Redox‐Immune Regulation and Mitochondrial Protection in Infected Diabetic Wound Healing

Advanced Science, EarlyView.
ABSTRACT Infected diabetic wounds are sustained by a vicious cycle of hyperglycemia‐driven bacterial infection, persistent oxidative stress, and excessive inflammation, which collectively disrupt the ordered progression of tissue repair. Here, we engineered a stage‐adaptive Janus microneedle patch (MN‐FeSAC‐PPE) to enable a staged therapeutic process ...
Mengting Yin, Yu Zhang, Xinyu Qu, Jiayi Liu, Zhongyi Sun, Haibo Liu, Ziyan Chen, Jing Ru, Jingwen Han, Bingqiang Lu, Yan Lu, Yan Wang, Xinyu Zhao, Feng Chen   +13 more
wiley   +1 more source

Diurnal Variation and Spatial Distribution Effects on Sulfur Speciation in Aerosol Samples as Assessed by X-Ray Absorption Near-Edge Structure (XANES)

Journal of Analytical Methods in Chemistry, 2012
This paper focuses on providing new results relating to the impacts of Diurnal variation, Vertical distribution, and Emission source on sulfur K-edge XANES spectrum of aerosol samples.
Siwatt Pongpiachan, Kanjana Thumanu, Warangkana Na Pattalung, Phoosak Hirunyatrakul, Itthipon Kittikoon, Kin Fai Ho, Junji Cao   +6 more
doaj   +1 more source

Oxygen Vacancy‐Enriched Platinum Single‐Atom Nanozyme Wrapped in Nanoislands: Unlocking Catalytic Activity and Reprogramming Redox Microenvironment for Osteonecrosis Repair

Advanced Science, EarlyView.
CeO2‐x/Pt single‐atom nano‐island is constructed via low‐temperature reduction, featuring abundant oxygen vacancies and an island–sea structure. It delivers outstanding multi‐enzyme‐mimetic activity and ROS‐scavenging efficiency. Density functional theory reveals optimized electronic structures and reaction pathways.
Yang Zhu, Zehui Lv, Xuejie Cai, Penghui Wei, Dengliang Wang, Zhao Wang, Ruoying Wang, Yingjie Wang, Xingdong Yang, Yixin Bian, Jiawei Xu, Xisheng Weng, Liangfeng Wei   +12 more
wiley   +1 more source

Improving sensitivity of XANES structural fit to the bridged metal–metal coordination

Journal of Synchrotron Radiation
Hard X-ray absorption spectroscopy is a valuable in situ probe for non-destructive diagnostics of metal sites. The low-energy interval of a spectrum (XANES) contains information about the metal oxidation state, ligand type, symmetry and distances in the ...
S. V. Abrosimov, B. O. Protsenko, A. S. Mannaa, V. G. Vlasenko, S. A. Guda, I. A. Pankin, A. S. Burlov, Y. V. Koshchienko, A. A. Guda, A. V. Soldatov   +9 more
doaj   +1 more source

XANE: eXplainable Acoustic Neural Embeddings

Interspeech 2024
We present a novel method for extracting neural embeddings that model the background acoustics of a speech signal. The extracted embeddings are used to estimate specific parameters related to the background acoustic properties of the signal in a non-intrusive manner, which allows the embeddings to be explainable in terms of those parameters.
Sri Harsha Dumpala, Dushyant Sharma, Chandramouli Shama Sastry, Stanislav Yu. Kruchinin, James Fosburgh, Patrick A. Naylor   +5 more
openaire   +2 more sources