Results 71 to 80 of about 21,282 (312)

Operando X‐Ray Absorption Spectroscopy Reveals Dynamic Interfacial Metal–Metal Coordination Governing CO2 Reduction Selectivity in PdAg Alloys

Advanced Materials Interfaces, EarlyView.
Operando X‐ray absorption spectroscopy uncovers dynamic Ag–Pd coordination in PdxAg1−x electrocatalysts during CO2 reduction. Partial oxidation of Ag and composition‐dependent metal–metal bonding synergistically regulate intermediate binding, enabling ∼91% CO selectivity.
Ruspika Sundaresan, Pandiyarajan Anand, Li‐Ling Lin, Naveen Karuppusamy, Hsu‐Feng Lee, Shin‐Yu Chang, Tsu‐Hao Chang, Yu‐Cheng Shao, Ching‐Wei Tung   +8 more
wiley   +1 more source

X-ray absorption spectroscopy of lanmodulin-derived peptides bound to rare earth elements

Journal of Synchrotron Radiation
A sustainable and robust supply chain of rare earth elements (REEs) is necessary to meet our consumer, national security and clean energy goals. However, current intra-REE separation technologies (e.g.
Adam Smerigan, Adam S. Hoffman, Jorge Perez-Aguilar, Rui Shi, Simon R. Bare   +4 more
doaj   +1 more source

Synchrotron‐Based Nano‐X‐Ray Absorption Near‐Edge Structure Revealing Intracellular Heterogeneity of Iron Species in Magnetotactic Bacteria

Small Science, 2022
Magnetotactic bacteria (MTB) sequester iron from the environment to biomineralize magnetite or greigite nanoparticles in magnetosome organelles, though the necessity of intracellular iron storage for the formation process is still in question ...
Daniel M. Chevrier, Elisa Cerdá-Doñate, Yeseul Park, Fernando Cacho-Nerin, Miguel Gomez‐Gonzalez, René Uebe, Damien Faivre   +6 more
doaj   +1 more source

The Influence of Mesoscale Particle Structure on the Electrode Degradation and Resultant Electrochemistry of Lithium Ion Cells With Nickel Rich Lithium Nickel Manganese Cobalt Oxide Positive Electrodes

Advanced Materials Technologies, EarlyView.
Milled polycrystalline NMC811 cathode (MPC NMC) with smaller secondary particle and higher surface area had 1) greater cathode tortuosity, 2) reduced surface Ni on the cycled MPC cathodes consistent with surface reconstruction, and 3) increased Ni deposition from cathode‐anode crosstalk, manifesting in lower functional capacity and higher impedance ...
Edelmy J. Marin Bernardez, Andrew Nicoll, David J. Arnot, Armando Rodriguez Campos, Patrick J. Barry, Marie F. Millares, Cynthia Huang, Melissa A. Guercio, Grace K. Dono, Alexis Pace, Xianghui Xiao, Cherno Jaye, Conan Weiland, Jianming Bai, Hui Zhong, Michael Drakopoulos, Zhong Zhong, Nghia T. Vo, Xiao Tong, Esther S. Takeuchi, Amy C. Marschilok, Shan Yan, Kenneth J. Takeuchi   +22 more
wiley   +1 more source

Elucidando os estados de oxidação do nitrogênio através da espectroscopia de absorção de raios-X na borda K do nitrogênio Nitrogen oxidation states elucidated by X-ray absorption nitrogen K-edge spectroscopy

Química Nova, 2006
The potentialities of X-ray Absorption Near Edge Spectroscopy (XANES) of the N K edge (N K) obtained with the spherical grating monochromator beam line at the Brazilian National Synchrotron Light Laboratory are explored in the investigation of poly ...
Gustavo M. do Nascimento, Marcia L. A. Temperini   +1 more
doaj   +1 more source

Atomic Tuning of Metal‐Support Interactions for Pathway‐Selective CO2 Photoreduction on TiO2

Advanced Science, EarlyView.
Single‐atom Fe and Cu catalysts anchored on TiO2 steer photocatalytic CO2 reduction toward distinct pathways. Fe sites favor rapid *CO desorption and selective CO formation, whereas Cu sites stabilize *CHO intermediates, enabling deep reduction and C─C coupling. Combined spectroscopy and DFT calculations reveal how metal–support interactions and oxygen
Dongyun Kim, Wonjae Ko, Byoung‐Hoon Lee, Sanghoon Kim, Yun Do Kim, Hyunsoo Ahn, Yoon Jung, Chan Woo Lee, Kug‐Seung Lee, Eunhee Gong, Junho Lee, Minho Kim, Taeghwan Hyeon, Su‐Il In   +13 more
wiley   +1 more source

K-edge XANES spectra data

, 2018
K-edge XANES spectra data computed using ...
Donald Winston (2161459), John J Rehr (5560889), Shyue Ping Ong (1350279), Chen Zheng (1652125), Kiran Mathew (1400941), Kristin A Persson (4613803), Alan Dozier (2409034), Chi Chen (67021)   +7 more
core   +1 more source

MetalCenter‐Dependent Selectivity Divergence in MN4 Single‐Atom Catalysts for Aerobic HMF Oxidation

Advanced Science, EarlyView.
Two single‐atom catalysts with M‐N4 configurations (FeN4 and CoN4) were developed for selective HMF oxidation. FeN4 achieves 93.9% selectivity toward FFCA via superoxide anions (O2•−), while CoN4 preferentially produces FDCA through hydroxyl radicals (•OH). DFT calculations reveal that distinct adsorption energies and charge redistribution at the metal
Haoyu Wang, Zhilong Ye, Weihao Wang, Zhi Hu, Qing Tian, Jie Gao, Lianbing Zhang   +6 more
wiley   +1 more source

Machine learning for efficient grazing-exit x-ray absorption near edge structure spectroscopy analysis: Bayesian optimization approach

Machine Learning: Science and Technology
In materials science, traditional techniques for analyzing layered structures are essential for obtaining information about local structure, electronic properties and chemical states.
Cafer Tufan Cakir, Can Bogoclu, Franziska Emmerling, Christina Streli, Ana Guilherme Buzanich, Martin Radtke   +5 more
doaj   +1 more source

Iron speciation in soils and soil aggregates by synchrotron-based X-ray microspectroscopy (XANES, mu-XANES)

, 2007
Iron speciation in soils is still poorly understood. We have investigated inorganic and organic standard substances, diluted mixtures of common Fe minerals in soils (pyrite, ferrihydrite, goethite), soils in a forested watershed which constitute a ...
Eusterhues, Karin, Eichert, Diane, Prietzel, Joerg, Thieme, Juergen   +3 more
core   +1 more source