Results 71 to 80 of about 39,813 (246)

Elucidando os estados de oxidação do nitrogênio através da espectroscopia de absorção de raios-X na borda K do nitrogênio Nitrogen oxidation states elucidated by X-ray absorption nitrogen K-edge spectroscopy

Química Nova, 2006
The potentialities of X-ray Absorption Near Edge Spectroscopy (XANES) of the N K edge (N K) obtained with the spherical grating monochromator beam line at the Brazilian National Synchrotron Light Laboratory are explored in the investigation of poly ...
Gustavo M. do Nascimento, Marcia L. A. Temperini   +1 more
doaj   +1 more source

Tailoring K+/Vacancy Disordered Layered Oxide via Charge Engineering for Stabilizing High‐Performance Potassium‐Ion Batteries

Advanced Functional Materials, EarlyView.
With a charge‐ion coupling engineering strategy, a K+/vacancy disordered K0.5Mn0.8Co0.1Ti0.1O2 material has been designed. The targeted transition metal doping disrupts charge ordering and inducing K+/vacancy disordering, thereby enabling rapid K+ diffusion through interconnected channels and a stable solid‐solution reaction mechanism.
Yongfeng Jia, Xuanpeng Wang, Jiashen Meng, Lujun Zhu, Fanjie Xia, Hong Wang, Fang Liu, Xiao Zhang, Quanquan Pang, Jian Wang, Zhitong Xiao   +10 more
wiley   +1 more source

Angular dependence of core hole screening in LiCoO2: A DFT+U calculation of the oxygen and cobalt K-edge x-ray absorption spectra

, 2009
Angular dependent core-hole screening effects have been found in the cobalt K-edge x-ray absorption spectrum of LiCoO2, using high-resolution data and parameter-free GGA+U calculations.
Amélie Juhin, Christian Brouder, F. M. F. de Groot, Frank de Groot, György Vankó, Matteo Calandra   +5 more
core   +3 more sources

Single‐ and Dual‐Atom Configurations in Atomically Dispersed Catalysts for Lithium–Sulfur Batteries

Advanced Functional Materials, EarlyView.
Single‐atom and dual‐atom‐based atomically dispersed catalysts (ADCs) effectively address the shuttle effect and sluggish redox kinetics in Li–S batteries. With nearly 100% atomic utilization and tunable coordination environments, ADCs enhance LiPSs adsorption, lower conversion barriers, and accelerate sulfur redox reactions.
Haoyang Xu, Zhenfeng Li, Yue Fei, Ali Mohammadi, Ge Li   +4 more
wiley   +1 more source

XANES spectra of forsterite in crystal, surface, and amorphous states

AIP Advances, 2018
The electronic structures of forsterite and its amorphous state were investigated using soft X-ray absorption near-edge structure (XANES) analysis at the Mg, Si, and O K-edges.
Osamu Takahashi, Yusuke Tamenori, Taiga Suenaga, Tomoko Ikeda-Fukazawa, Junya Matsuno, Akira Tsuchiyama   +5 more
doaj   +1 more source

Rate‐Adaptive Site Transformation Catalyst for Parallel Water Dissociation and Hydrogen Adsorption in Alkaline Hydrogen Evolution

Advanced Functional Materials, EarlyView.
This work presents a rate‐adaptive site transformation strategy in Ag‑ethylenediamine intercalated Co9S8, which not only enables parallel water dissociation and H* adsorption, but also allows the catalyst to provide more active sites under high demand, removing a major bottleneck. The catalyst achieves a record current density of 4.2 A cm−2@2.0 V, with
Yongqi Ye, Yuzhuo Jiang, Bin Tian, Derek Ho   +3 more
wiley   +1 more source

Machine learning for efficient grazing-exit x-ray absorption near edge structure spectroscopy analysis: Bayesian optimization approach

Machine Learning: Science and Technology
In materials science, traditional techniques for analyzing layered structures are essential for obtaining information about local structure, electronic properties and chemical states.
Cafer Tufan Cakir, Can Bogoclu, Franziska Emmerling, Christina Streli, Ana Guilherme Buzanich, Martin Radtke   +5 more
doaj   +1 more source

Synthesis and characterization of nanocrystalline U1-xPuxO2(+y) mixed oxides

Materials Today Advances, 2020
We report here the first synthesis of mixed oxide U1-xPuxO2(+y) nanoparticles. The obtained nanopowders were characterized by X-ray diffraction, thermal ionization mass spectrometry, transmission electron microscopy, Raman spectroscopy, and U M4 edge ...
G. Kauric, O. Walter, A. Beck, B. Schacherl, O. Dieste Blanco, J.-F. Vigier, E. Zuleger, T. Vitova, K. Popa   +8 more
doaj   +1 more source

Balancing Electrons to Break the Activity‐Selectivity Trade‐Off in H2O2 Electrosynthesis

Advanced Functional Materials, EarlyView.
Carrier‐concentration balancing in CuS is achieved by coupling cobalt dopants with cobalt vacancies, converting CuS from p‐ to n‐type to accelerate 2e− ORR while withdrawing excess carriers to optimize *OOH binding for H2O2 desorption. The catalyst reaches 8.14 mol g−1 h−1 with >84% selectivity in 1.0 M KOH and drives robust electro‐Fenton dye ...
Hangning Liu, Changhui Sun, Luyao Wang, Yuhang Cheng, Yi Xin, Xuyun Guo, Hui Li, Valeria Nicolosi, Yuhai Dou, Peng Li, Tianyi Ma, Jie Wang   +11 more
wiley   +1 more source

High‐Performance Electrocatalysts of Potassium Lactate Oxidation for Hydrogen and Solid Potassium Acetate Production

Advanced Materials, Volume 37, Issue 13, April 2, 2025.
Potassium lactate, produced from polylactic acid plastic waste, is oxidized to potassium acetate on an anode using Ni(Co)OOH as the electrocatalyst, while hydrogen is simultaneously generated at the cathode, through a highly efficient industrial‐scale electrolysis system.
Jun Hu, Xintong Gao, Shanqing Li, Zhongsheng Xie, Xinyu Sheng, Zhixiang Yuan, Fei Zhang, Ping Chen, Yao Zheng, Shi‐Zhang Qiao   +9 more
wiley   +1 more source