Synthesis of Isotactic Polybutene-1 with Ziegler-Natta Catalyst [PDF]
علوم و تکنولوژی پلیمر, 2022 Hypothesis: Butene-1 is in excess in the polyolefin plants of Iran. Considering the properties of isotactic polybutene-1, including high creep and environmental stress cracking resistances, excellent elastic reversibility and good chemical abrasion ...
shokoufeh Hakim +2 more
doaj +1 more source
The monopotassium salt of the ligand of a Ziegler–Natta catalyst [PDF]
, 1993 The anion of dipotassium (tert-butylamino)-dimethyl(tetramethylcyclopentadienyl)silanediide can coordinate to transition metals to form precursors for single-component Ziegler-Natta polymerization catalysts.
Bercaw, John E. +2 more
core +1 more source
Beneficial influence of nanocarbon on the aryliminopyridylnickel chloride catalyzed ethylene polymerization [PDF]
, 2013 A series of 1-aryliminoethylpyridine ligands (L1―L3) was synthesized by condensation of 2-acetylpyridine with 1-aminonaphthalene, 2-aminoanthracene or 1-aminopyrene, respectively.
Durand, Jérôme +6 more
core +4 more sources
Immobilizing metallocene by solid polymethylaluminoxane “sMAO” for slurry-phase ethylene-1-hexene copolymerization [PDF]
MATEC Web of Conferences, 2022 In the field of olefin catalytic polymerization, metallocene catalysts show higher activity than traditional Ziegler-Natta catalysts. In this study, benzoic acid catalyzed the controlled hydrolysis of trimethylaluminum (TMA) to methylaluminoxane (MAO ...
Wu Chaofan +5 more
doaj +1 more source
Catalysts, 2020 Polypropylene/molybdenum disulfied (PP/MoS2) and Polypropylene/hexagonal boron nitride (PP/hBN) nanocomposites with varying concentration (0–6 wt %) were fabricated via in situ polymerization using two-dimensional (2D)-nanosheet/MgCl2-supported Ti-based ...
Zhang Hexin +3 more
semanticscholar +1 more source
Synthesizing polypropylene with percolation network catalyzed by inorganic nanoparticles-functionalized Ziegler-Natta catalyst [PDF]
Polyolefins JournalPolypropylene is one of the most widely used synthetic resins, which is mainly synthesized with Ziegler-Natta catalysts. In this paper, the functionalized Ziegler-Natta catalyst is applied to prepare high-performance polypropylene.
Tingting Yang +3 more
doaj +1 more source
Comparative simulation study of gas-phase propylene polymerization in fluidized bed reactors using aspen polymers and two phase models [PDF]
, 2012 A comparative study describing gas-phase propylene polymerization in fluidized-bed reactors using Ziegler-Natta catalyst is presented. The reactor behavior was explained using a two-phase model (which is based on principles of fluidization) as well as
Hussaina M.A. +3 more
core +1 more source
イソニトリルの重合と金属錯体との反応に関する研究 [PDF]
, 2009 Trace amounts of Pt- and Ru-doped Ni/Mg(Al)O catalysts were prepared by a citrate method and tested in the oxidative reforming of C3H8 under daily start-up and shut-down (DSS) operation.
Li, Dalin +6 more
core +3 more sources
Crystal structures and polymorphism of polymers: Influence of defects and disorder [PDF]
, 2018 The crystal structures and the polymorphism of polymers are described on the basis of the main principles that define the conformation of polymer chains in the crystalline state and the modes of packing of macromolecules.
Auriemma, Finizia +3 more
core +1 more source
What do We Know about Reaction Mechanism? The Electrospray Ionization Mass Spectrometry Approach [PDF]
, 2011 Santos, LS (reprint author), Univ Talca, Lab Asymmetr Synth, POB 747, Talca, Chile.Man's fascination with chemical reactions goes back to ancient times.
Santos, L.S.
core +2 more sources