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Boryl Azides in 1,3-Dipolar Cycloadditions
The Journal of Organic Chemistry, 2014The 1,3-dipolar cycloaddition reaction of boron azides with alkynes has been investigated experimentally and computationally. At room temperature pinBN3 (pin = pinacolato) reacts with the strained triple bond of cyclooctyne with formation of an oligomeric boryl triazole.
Matthias, Müller +2 more
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Asymmetric 1,3-dipolar cycloadditions of acrylamides
Chem. Soc. Rev., 2010This critical review, which is relevant to researchers in synthetic organic chemistry, focuses on asymmetric 1,3-dipolar cycloadditions with acrylamides. The use of chiral acrylamides as dipolarophiles leads to high levels of stereocontrol, due to conformational constraint in the acrylamides.
Marie, Kissane, Anita R, Maguire
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1994
Von Huisgen 1,2) wurde 1963 die 1,3-dipolare Cycloaddition 3–5) als Reaktionsprinzip zum Aufbau von Heterocyclen systematisiert. Man versteht darunter die Addition eines 1,3-Dipols 1, der aus den verschiedenen Kombinationen von Kohlenstoff-, Stickstoff- und Sauerstoffatomen bestehen kann und vier nicht dienische π-Elektronen umfast, an eine ...
Thomas Laue, Andreas Plagens
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Von Huisgen 1,2) wurde 1963 die 1,3-dipolare Cycloaddition 3–5) als Reaktionsprinzip zum Aufbau von Heterocyclen systematisiert. Man versteht darunter die Addition eines 1,3-Dipols 1, der aus den verschiedenen Kombinationen von Kohlenstoff-, Stickstoff- und Sauerstoffatomen bestehen kann und vier nicht dienische π-Elektronen umfast, an eine ...
Thomas Laue, Andreas Plagens
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Transition Metal Complexation in 1,3-Dipolar Cycloadditions
HETEROCYCLES, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
BROGGINI, GIANLUIGI +3 more
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1,3‐Dipolar cycloadditions to alkyldicyanamides
Recueil des Travaux Chimiques des Pays-Bas, 1981AbstractThe 1,3‐dipoles 2,4,6‐trimethylbenzonitrile oxide and benzyl azide react with alkyldicyanamides (1) to give the 3,5‐disubstituted 1,2,4‐oxadiazoles 2 and the 1,5‐disubstituted tetrazole 4, respectively, by (3 + 2)‐cycloaddition. The structure of 4 has been determined by a single crystal X‐ray analysis.
P. H. Benders +2 more
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1,3-dipolar cycloadditions to oxidopyraziniums
Tetrahedron Letters, 1987Abstract 1,5-Dimethyl-3-oxidopyrazinium (6) undergoes cycloadditions with methyl acrylate, acrylonitrile, diethyl maleate, maleimide, methyl propiolate and diethyl acetylenedicarboxylate.
Miklos Kiss +2 more
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Concertedness of 1,3-dipolar cycloadditions
Journal of Chemical Education, 1984The 1,3-dipolar cycloaddition is the union of a 1,3-dipole with a multiple bond system (a dipolarophile) to form a five-membered ring; the process is regarded as one of the most general methods for the synthesis of five-membered heterocycles.
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1,3-dipolar cycloadditions with porphyrins
2009The objective of this work is to use 1,3-dipolar cycloadditions to synthesize novel aromatic compounds based on meso-phenyl substituted porphyrins. These compounds are potential photosensitizers for use in photodynamic therapy. Tetraphenylporphyrins with a variety of substituents were reacted with selected 1,3-dipoles.
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