Results 111 to 120 of about 46,711 (243)

Ullmann‐Type N‐Heteroarylation of Nitrogen Heterocycles Catalyzed by Heterogeneous CuNPs/HKUST‐1

EcoEnergy, EarlyView.
A practical strategy for the direct synthesis of CuNPs/HKUST‐1 heterogeneous catalyst was developed and used for the catalyzing Ullmann‐type N‐arylation of N‐heterocycles with high yields, excellent recyclability, and low copper leaching. ABSTRACT Ullmann‐type C–N coupling is an essential reaction to construct functional nitrogen heterocycles, whereas ...
Shuai Yang, Fangshu Han, Yamin Dong, Liangting Wu, Wenchao Tang, Changyan Guo, Jide Wang, Ablimit Abdukader, Chenjiang Liu, Yonghong Zhang   +9 more
wiley   +1 more source

A Mixed‐Ligand Metal–Organic Framework Strategy to Construct High‐Density O/S‐Shelled Ag Nanoparticle Electrocatalysts for Syngas Modulation

EcoEnergy, EarlyView.
Mixed‐ligand Ag–triazole MOF precursors reconstruct into ligand‐shelled Ag nanoparticle electrocatalysts that retain detectable O/S‐derived interfacial species. By combining ligand‐ratio and potential control, the CO2‐to‐syngas output can be tuned across H2‐rich, near‐equimolar, and CO‐rich regimes.
Ren‐Feng Yang, Xu‐Dong Wu, Yu‐Die Zhang, Wei‐Peng Chen, Xiao‐Hui Li, Qi Zhou, Kai‐Zhong Zhang, Xian‐Yue Song, Hao‐Ran Chu, Hai‐Feng Zhang, Xiao‐Hong Xiong, Mian Li, Xiao‐Chun Huang   +12 more
wiley   +1 more source

Ambient Electrosynthesis of Pure 15 wt% H2O2 Without Salt Using an Ultrathin Metal–Organic Framework Nanosheet Featuring Dicopper(I) Active Sites

EcoEnergy, EarlyView.
An ultrathin metal–organic framework nanosheet with exposed dicopper(I) active sites enables ambient electrosynthesis of pure, salt‐free 15 wt% H2O2, achieving ∼95% Faradaic efficiency, 350 mA cm−2 current density, and over 50 h of stable operation in a solid‐electrolyte system.
Ze‐Wei Chai, Pei‐Qin Liao
wiley   +1 more source

Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles

European Journal of Organic Chemistry, EarlyView.
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu, Mauro Uras, Angelo Frongia   +2 more
wiley   +1 more source

Chelation‐Assisted Metal‐Catalyzed Ligation and Cleavage Reactions for Chemical Biology

European Journal of Organic Chemistry, EarlyView.
Chelation‐assisted transition metal catalysis has emerged as a promising complement to bioorthogonal click chemistry for studying biological processes. By pre‐organizing catalytic metal centers, designed coordinating substrates enhance reactivity and biocompatibility, enabling site‐selective ligation and decaging reactions in complex biological media ...
Emilie Plantiveau, Maxime Riberaud, Frédéric Taran, Antoine Sallustrau   +3 more
wiley   +1 more source

Molecular insights into triazole-based compounds for triple-negative breast cancer treatment. [PDF]

J Enzyme Inhib Med Chem
Vilangalil A, E S SP, Bukke SPN, V S, Meha N, Thalluri C, Daniel K, Ahikiriza AA.   +7 more
europepmc   +1 more source

Selective N‐Functionalization of Pyrazoles

European Journal of Organic Chemistry, EarlyView.
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek, Matthias Schrader, Christopher J. Teskey   +2 more
wiley   +1 more source

Click Bioconjugation of Aza‐BODIPY Fluorophores to LfcinB Peptides for Improved Biocompatibility

European Journal of Organic Chemistry, EarlyView.
Click bioconjugation attaches NIR aza‐BODIPY fluorophores to LfcinB‐derived anticancer peptides via CuAAC and thiol‐maleimide chemistry. Conjugates exhibit improved predicted solubility while retaining strong NIR absorption (703–730 nm). Peptide‐aza‐BODIPY conjugates induce apoptotic morphology in HeLa cancer cells.
A. Verónica Rodríguez‐Mayor, Maricela Morales, Héctor Manuel Pineda‐Castañeda, Zuly Jenny Rivera‐Monroy, Javier Eduardo García‐Castañeda, Norberto Farfán, Rosa Santillan   +6 more
wiley   +1 more source

Novel Peptide-Triazole Conjugates: Strategic Synthesis, Antimicrobial Properties, and Molecular Docking Study. [PDF]

J Pept Sci
Bhavsar J, Tivari S, Pati SS, Bhanderi P, Makwana B, Khunt R, Kumar N, Chaturvedi VK, Singh R.   +8 more
europepmc   +1 more source

Recent advances and prospects for high‐efficiency blue hot exciton organic light‐emitting diodes

FlexMat, EarlyView.
Blue organic light‐emitting diodes (OLEDs) face great challenges in achieving the balance between color purity, device efficiency, and stability. Hot exciton materials offer a solution by rapidly converting non‐emissive triplet excitons into singlet ones through a high‐lying reverse intersystem crossing process.
Xiaoen Shi, Shuyuan Ge, Futong Liu, Ping Lu   +3 more
wiley   +1 more source