Synthesis and Application of Bioactive N-Functionalized Aziridines. [PDF]
Angew Chem Int Ed EnglThis review discusses modern synthetic methods for the preparation of aziridine‐containing small molecules, including biocatalytic, electrocatalytic, and photocatalytic strategies. We highlight the compatibility of various synthetic methods with control of the exocyclic N‐substituent.
Tan H +4 more
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Intermolecular Alkyl Radical Addition to Methyl 2‐(2,6‐Dichlorophenyl)‐2H‐azirine‐3‐carboxylate. [PDF]
, 2003 The 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane. The addition proceeds with high regio- and diastereo-selectivity.The present work has been supported by Fundação para a Ciência e ...
M. José Alves +3 more
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Ethyl 2-(Diisopropoxyphosphoryl)-2H-Azirine-3-Carboxylate: Reactions with Activated 1,3-Butadienes [PDF]
, 2008 The 12th International Electronic Conference on Synthetic Organic Chemistry session General Organic SynthesisEthyl 2-(diisopropoxyphosphoryl)-2H-azirine-3-carboxylate was generated “in situ” and reacted with a number of 1,3-butadienes.
M. José Alves +3 more
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Synthesis of Biologically active 2H-azirines-A review
Journal of Scientific Enquiry, 2022 Aramita De, Adinath Majee
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Synthesis of 2-halo-2H-azirines [PDF]
Tetrahedron, 2001 Abstract α-Oxophosphonium ylides react with N -chlorosuccinimide, N -bromosuccinimide and N -iodosuccinimide in the presence of azidotrimethylsilane giving the corresponding haloazidoalkenes which were completely converted to the 2-halo-2 H -azirines on heating in heptane.
Pinho e Melo, Teresa M. V. D. +3 more
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STUDY BASED ON ELECTRONIC DESCRIPTORS OF THE DIASTEREOSELECTIVE AZA-DIELS-ALDER CYCLOADDITION OF [(1R)-10-(N,N-DIETHYLSULFAMOYL)ISOBORNYL] 2H-AZIRINE-3-CARBOXYLATE TO E,E-1,4-DIACETOXY-1,3-BUTADIENE [PDF]
, 2013 Cycloaddition of chiral [(1R)-10-(N,N-diethylsulfamoyl)isobornyl] 2H-azirine-3-carboxylate to E,E-1,4-diacetoxy-1,3-butadiene shows complete diatereoselectivity giving a single cycloadduct (-)-(2S,5R,6R)-6-[(1R)-10-(N,N-diethylsulfamoyl ...
Yasser B. Ruiz‐Blanco +3 more
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Synthesis of 2-(Trifluoromethyl)Azetidines by Strain-Release Reactions of 2-(Trifluoromethyl)-1-Azabicyclo[1.1.0]Butanes. [PDF]
Chemistry2‐(Trifluoromethyl)‐1‐azabicyclo[1.1.0]butanes, available by diastereoselective cyclopropanation of 2‐(trifluoromethyl)‐2H‐azirines, can be successfully involved in strain‐release ring‐opening processes, as illustrated by their reaction with benzyl chloroformate, trifluoroacetic anhydride or palladium‐catalyzed hydrogenolysis.
Scuiller A +7 more
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Polymerization-Induced Direct Photolithography of Quantum Dots. [PDF]
Macromol Rapid CommunWe present a comprehensive overview of photochemical polymerization strategies for direct lithographic patterning of colloidal quantum dots (QDs). Reaction mechanisms are categorized by functional group type, and their application is discussed in terms of pattern fidelity, photostability, and environmental robustness, highlighting the potential of ...
Kim T, Gwak N, Oh N, Kim TA.
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Diels–Alder reactions of alkyl 2H-azirine-3-carboxylates with furans [PDF]
, 2001 Methyl 2-(2,6-dichlorophenyl)-2H-azirine-3-carboxylate 1 and furan give the aziridine 2 by a Diels–Alder cycloaddition reaction. The hydrolysis of compound 2 leads to a dihydrofuranol 11 by cleavage of a C–N bond.
M. José Alves +5 more
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The Thermal Reactions of 2H-Azirines
HETEROCYCLES, 1977 Hiroshi Taniguchi +2 more
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