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Hydrolytic degradation of poly[(R)-3-hydroxybutyric acid] in the melt

Polymer, 2005
Abstract Poly[(R)-3-hydroxybutyric acid] [R-P(3HB)] was hydrolyzed in high-temperature and high-pressure water at the temperature range of 180–300 °C and for a period of 360 min. The formation, racemization, and decomposition of 3-hydroxybutyric acids (3HBs) and molecular weight change of R-P(3HB) were investigated.
Takashi Saeki   +4 more
openaire   +1 more source

Accumulation of 3-hydroxyisobutyric acid, 2-methyl-3-hydroxybutyric acid and 3-hydroxyisovaleric acid in ketoacidosis

Clinica Chimica Acta, 1975
1. Urine and serum samples from patients with ketoacidosis of varying degree and etiology have been examined by gas chromatography and mass spectrometry. 2. In addition to 3-hydroxyisovaleric acid, relatively high concentrations of two analogous hydroxy acids, 3-hydroxyisobutyric acid and 2-methyl-3-hydroxybutyric acid, were found in the urine.
openaire   +2 more sources

Biosynthesis of enantiopure (S)-3-hydroxybutyric acid in metabolically engineered Escherichia coli

Applied Microbiology and Biotechnology, 2008
A biosynthetic pathway for the production of (S)-3-hydroxybutyric acid (S3HB) from glucose was established in recombinant Escherichia coli by introducing the beta-ketothiolase gene from Ralstonia eutropha H16, the (S)-3-hydroxybutyryl-CoA dehydrogenase gene from R.
Lee, SH   +3 more
openaire   +3 more sources

Nutritional and cultural conditions for production of poly-3-hydroxybutyric acid byAzotobacter chroococcum

Folia Microbiologica, 1998
Free-living nitrogen-fixing bacteria have been identified as a potential source of poly-3-hydroxybutyric acid (PHB). Systematic study of this ability of N(2)-fixing organisms has lead to the isolation of an efficient strain, identified asAzotobacter chroococcum.
S, Pal, A, Manna, A K, Paul
openaire   +2 more sources

Enzymatic reduction of levulinic acid by engineering the substrate specificity of 3-hydroxybutyrate dehydrogenase

Bioresource Technology, 2013
Enzymatic reduction of levulinic acid (LA) was performed for the synthesis of 4-hydroxyvaleric acid (4HV)--a monomer of bio-polyester and a precursor of bio-fuels--using 3-hydroxybutyrate dehydrogenase (3HBDH) from Alcaligenes faecalis. Due to the catalytic inactivity of the wild-type enzyme toward LA, engineering of the substrate specificity of the ...
Young Joo, Yeon   +2 more
openaire   +2 more sources

Production of (R)-3-hydroxybutyric acid by fermentation and bioconversion processes with Azohydromonas lata

Bioresource Technology, 2011
Feasibility of producing (R)-3-hydroxybutyric acid ((R)-3-HB) using wild type Azohydromonas lata and its mutants (derived by UV mutation) was investigated. A. lata mutant (M5) produced 780 m g/l in the culture broth when sucrose was used as the carbon source.
Charles U, Ugwu   +2 more
openaire   +2 more sources

Infrared analysis on blends of poly(3‐hydroxybutyric acid) and stereoregular poly(vinyl alcohol): influence of tacticity of poly(vinyl alcohol) on crystallization of poly(3‐hydroxybutyric acid)

Macromolecular Chemistry and Physics, 1996
AbstractThe extens of crystallization of poly(3‐hydroxybutyric acid) (P(3HB)) in blends of P(3HB) with stereoregular poly(vinyl alcohol) (PVA) have been studied by means of infared spectroscopy. The degree of crystallinity of P(3HB) was found to decrease by blending with atactic PVA when PVA was the predominant component of the blend.
Tetsuya Ikejima   +2 more
openaire   +1 more source

Effect of Benzoic Acid on the Crystallization Behavior of Poly(3-Hydroxybutyrate)

Journal of Macromolecular Science, Part B, 2013
The effect of benzoic acid (BA) on the crystallization behavior of poly(3-hydroxybut yrate; PHB) was studied.
openaire   +1 more source

Syntheses and condensation polymerizations of 3‐hydroxybutyric acid derivatives of pyrimidine bases

Die Makromolekulare Chemie, 1978
Abstract4‐(1,2,3,4‐Tetrahydro‐5‐methyl‐2,4‐dioxo‐1‐pyrimidinyl)‐3‐hydroxybutyric acid (1a) and 4‐(1,2,3,4‐tetrahydro‐2,4‐dioxo‐1‐pyrimidinyl)‐3‐hydroxybutyric acid (1b) were synthesized via the addition reaction of thymine (3) and 4‐ethoxy‐1,2‐dihydro‐2‐oxopyrimidine (7), respectively, to 1‐chloro‐2,3‐epoxypropane and subsequent cyanization, followed ...
Masahira Hattori   +2 more
openaire   +1 more source

Organocatalytic depolymerization of poly(3-hydroxybutyrate) to crotonic acid

Polymer Degradation and Stability, 2023
Qingfu Zhang   +5 more
openaire   +1 more source

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