Results 121 to 130 of about 47,847 (251)

A Mixed‐Ligand Metal–Organic Framework Strategy to Construct High‐Density O/S‐Shelled Ag Nanoparticle Electrocatalysts for Syngas Modulation

open access: yesEcoEnergy, EarlyView.
Mixed‐ligand Ag–triazole MOF precursors reconstruct into ligand‐shelled Ag nanoparticle electrocatalysts that retain detectable O/S‐derived interfacial species. By combining ligand‐ratio and potential control, the CO2‐to‐syngas output can be tuned across H2‐rich, near‐equimolar, and CO‐rich regimes.
Ren‐Feng Yang   +12 more
wiley   +1 more source

Ambient Electrosynthesis of Pure 15 wt% H2O2 Without Salt Using an Ultrathin Metal–Organic Framework Nanosheet Featuring Dicopper(I) Active Sites

open access: yesEcoEnergy, EarlyView.
An ultrathin metal–organic framework nanosheet with exposed dicopper(I) active sites enables ambient electrosynthesis of pure, salt‐free 15 wt% H2O2, achieving ∼95% Faradaic efficiency, 350 mA cm−2 current density, and over 50 h of stable operation in a solid‐electrolyte system.
Ze‐Wei Chai, Pei‐Qin Liao
wiley   +1 more source

Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu   +2 more
wiley   +1 more source

Chelation‐Assisted Metal‐Catalyzed Ligation and Cleavage Reactions for Chemical Biology

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Chelation‐assisted transition metal catalysis has emerged as a promising complement to bioorthogonal click chemistry for studying biological processes. By pre‐organizing catalytic metal centers, designed coordinating substrates enhance reactivity and biocompatibility, enabling site‐selective ligation and decaging reactions in complex biological media ...
Emilie Plantiveau   +3 more
wiley   +1 more source

Selective N‐Functionalization of Pyrazoles

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek   +2 more
wiley   +1 more source

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