Palladium is a simple and versatile redox‐active metal that plays a crucial role in the oxidation reactions for organic synthesis and production of pharmaceutical intermediates. Notably, there has been significant progress with Lewis acids (LAs), which are non‐redox metal ions promoting Pd(II)‐catalyzed oxidation via C—H and C—C bond activation.
Ahmed M. Senan +3 more
wiley +1 more source
6-Bromo-1-[2-(2-oxo-1,3-oxazolidin-3-yl)ethyl]-1H-imidazo[4,5-b]pyridin-2(3H)-one
The title compound, C11H11BrN4O3, features an ethane fragment substituted with an almost planar (r.m.s. deviation = 0.019 Å) imidazo[4,5-b]pyridone ring system and an envelope-shaped oxazolidine unit on separate C atoms.
H. Bel-Ghacham +4 more
doaj +1 more source
Synthesis of 2-Pyridone Derivatives Bearing an Electron-withdrawing Group on Nitrogen [PDF]
1-Protected 2(1H)-pyridones are highly useful dienophiles because Diels-Alder reaction of 1-sulfonyl-2(1H)-pyridones gave the synthetic intermediate such as quinoline and isoquinoline derivatives.
渡邉, 一弘 +8 more
core
Major Constituents of the Predominant Endophytic Fungi from the Nigerian Plants and
In a chemical screening of fungal strains endophytic to Nigerian plants, Diaporthe phaseolorum , the endophyte of Bryophyllum pinnatum , gave cytochalasin D and (3 R ,4 R )-3,4,5-trihydroxy-1-tetralone, Neurospora discreta from Morinda lucida yielded ...
Abimbola A. Sowemimo +5 more
doaj +1 more source
The photochemical[2 + 2]cycloaddition to N-methoxycarbonyl-5,6-dihydro-4-pyridone
The N-methoxycarbonyl-5,6-dihydro-4-pyridone (1) undergoes photochemical [2 + 2] cycloaddition with a series of differently substituted alkenes in high yield and with extremely high ...
Guerry, Philippe, Neier, Reinhard
core +1 more source
Pyridonderivate aus 3-Amino-2H-azirinen und Cyclopropenonen
Reaction of the 3-dimethylamino-2H-azirines 1a and 1b with diphenylcyclopropenone (2a) in ether or acetonitrile leads to the 2-dimethylamino-5,6-diphenyl-4(3H)-pyridones 3a and 3b in 70 and 80% yield, respectively. The structure of these 1:1-adducts has
Stanislav Chaloupka, Heinz Heimgartner
doaj +1 more source
catena-Poly[[[bis(2-pyridone-κO)sodium]-di-μ-2-pyridone-κ4O:O] tetrafluoroborate]
In the title compound, [Na(C5H5NO)(4)] BF4, each Na+ ion, lying on an inversion centre, is octahedrally coordinated by four bridging and two terminal pyridone ligands, creating a cationic coordination polymer chain with tetrafluoroborate anions occupying
Owen, Gareth R., Haddow, Mairi F.
core +1 more source
Synthesis of 5-(substituted phenylazo)-6-hydroxy-4-methyl-3-cyano-2-pyridones from ethyl 3-oxo-2-(substituted phenylazo)butanoates, Short communication [PDF]
A new procedure for the synthesis of known azo pyridone dyes is presented. A series of 5-(substituted arylazo)-6-hydroxy-4-methyl-3-cyano-2-pyridones were prepared from ethyl 3-oxo-2-(substituted phenylazo)butanoates and cyanoacetamide in acetone using ...
GORDANA UŠĆUMLIĆ +3 more
doaj
4-Pyridone-3-carboxamide-1-β-D-ribonucleoside (4PYR)-A Novel Oncometabolite Modulating Cancer-Endothelial Interactions in Breast Cancer Metastasis. [PDF]
Koszalka P +7 more
europepmc +1 more source
Brønsted acid catalyzed tandem cyclization was found to be highly effective for the preparation of a series of polysubstituted 4-pyrones from diynones (yield up to 99%).
Yu-Ying Ye (1554475) +7 more
core +3 more sources

