Reaction Engineering of In Vitro Natural Product Biosynthesis: Challenges and Strategies
ChemBioChem, EarlyView.The yield and turnover of in vitro natural product biosynthesis, and even its feasibility, are determined by intermolecular interactions. Reaction engineering allows to improve the performance of such complex biocatalytic systems. Natural products are widely used as pharmaceuticals and agrochemicals, or as active ingredients in food and cosmetics ...
Elsa Sánchez‐García +2 more
wiley +1 more source
Studies on γ-Butyrolactone Derivatives. III-IV. III. Acylation of α-Amino-γ-butyrolactone.
, 1958 須藤 六郎
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Analysis of mixtures of alcohols by acylation [PDF]
, 1961 William Dean Fellows
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C‐Acylation of Guaiacol with Acetic Acid Over Solid Acid Catalysts Under Mild Reaction Conditions
ChemCatChem, EarlyView.Direct acylation of guaiacol (G) with acetic acid (AA) over Aquivion® PW87 under mild conditions affords 4‐hydroxy‐3‐methoxyacetophenone (p‐HMAP) with a remarkable para/ortho molar ratio of 26:1. Combined DFT and experimental studies reveal an acid‐catalyzed intermolecular acyl transfer via 2‐methoxyphenyl acetate (MPA), enabling a highly selective and
Nicola Schiaroli +3 more
wiley +1 more source
Phenethyl alcohol inhibition of sn-glycerol 3-phosphate acylation in Escherichia coli [PDF]
, 1977 W D Nunn +4 more
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Photoswitching of the Two‐Photon Absorption of Donor‐Acceptor Substituted Dithienylethenes
ChemistryEurope, EarlyView.Switching two‐photon absorption: Donor‐acceptor substituted dithienylethenes are shown to switch their two‐photon absorption properties upon light‐induced electrocyclic isomerization. In this work the structural and electronic integration of push–pull systems with photoactivatable dithienylethenes (DTEs) is demonstrated.
Francisco G. Blandón‐Cumbreras +8 more
wiley +1 more source
SOME OBSERVATIONS ON THE MECHANISM OF THE ACYLATION PROCESS IN PROTEIN SYNTHESIS
, 1964 Beverly E. Griffin, Colin B. Reese
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Interactions of insulin and adrenaline with glycerol phosphate acylation processes in fat‐cells from rat [PDF]
, 1976 Suren R. Sooranna, E D Saggerson
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Photochemical Allylation of Aldehydes or Alkanes with Vinyl Cyclopropanes
ChemistryEurope, EarlyView.An acylation or alkylation of vinyl cyclopropanes, employing tetra‐n‐butylammonium decatungstate as the photocatalyst, leading allyl ketones or alkenes is presented. A diverse range of substrates were compatible with this protocol, while flow conditions were also developed and mechanistic studies were also performed.
Naya A. Stini, Christoforos G. Kokotos
wiley +1 more source
Kinetics of the reactions of the acid anhydrides with aromatic amines in aprotic solvents [PDF]
Work has revealed that diamine derivatives of diphenylmethane (IV), diphenyl ether (V), benzophenone (IV), fluorene (VII), and fluorenone (VIII) polymerizations with pyromellitic dianhydride in DMA were dependent on the basicity of the amine compound ...
Mason, J. G., Sugg, E.
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