Enriching Alkene <i>syn</i>-Dihalogenation: Aryl Alkene, Bromine, Regio-Reversion, and Stereoconvergency. [PDF]
Org LettMoon H, Hong J, Chung WJ.
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Aryl and Alkyl Radiotrifluoromethylation via Metallaphotoredox‐Mediated Radical Cross‐Coupling
Angewandte Chemie, EarlyView.The metallaphotoredox‐mediated radiotrifluoromethylation of arenes and alkanes is described. The operationally simple protocols make use of substrates bearing thianthrenium salts (TT) or N‐hydroxyphthalimide (NHPI) esters and CF218FI. The reaction proceeds through a Ru‐mediated radical formation followed by a Cu‐mediated radical cross‐coupling step and
Lukas Veth +2 more
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Synthesis of aliphatic α-hydroxy carboxylic acids <i>via</i> electrocarboxylation of aldehydes. [PDF]
RSC AdvOksanen V, Malinen K, Wirtanen T.
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ALIPHATIC CARBONYL COMPOUNDS: ALIPHATIC ALDEHYDES
, 1992 Fürstner, A., Weidmann, H.
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Angewandte Chemie, EarlyView.Precision hydrolysis enables the rational, room‐temperature synthesis of Zr and Hf oxo clusters with improved atom economy, sustainable solvents, and gram‐scale yields. By adding exactly 1.33 equivalents of water, Zr6, Hf6, and elusive bimetallic clusters are accessed, alongside new group 5 oxo clusters, providing a versatile and economical platform ...
Muhammed Jibin Parammal +5 more
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Stereodivergent Access to Aliphatic Nitro Compounds Bearing Multi-Contiguous Stereocenters via Sequential Catalysis. [PDF]
Adv Sci (Weinh)Xie JH, Hou YM, Wu ZJ, Zheng C, You SL.
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Regiodivergent C3 and C4 Amination of Quinolines via Radical and Ionic Pathways
Angewandte Chemie, EarlyView.A regiodivergent strategy converts a single N‐aminoquinolinium precursor into either C3‐ or C4‐aminated quinolines. Nucleophile‐induced dearomatization diverges into light‐driven N‐centered radical capture (C3) or base‐promoted SNAr (C4), enabling rapid assembly of aminoquinoline libraries and late‐stage diversification.
Ye‐Eun Kim +3 more
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Carbon Structure Evolution of Middle- and High-Rank Coal during Coalification: Implication for Methane Production and Adsorption. [PDF]
ACS OmegaWang M +6 more
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Direct Selection of Functional De Novo Macrocycles for Activation of On‐Cellulo Insulin Receptor
Angewandte Chemie, EarlyView.A live‐cell screening platform, RaPID‐ExCells, integrates mRNA display‐derived macrocyclic peptide libraries with functional selection against native cell‐surface receptors. Application to the insulin receptor enabled de novo discovery of a macrocyclic agonist that activates endogenous signaling despite weak in vitro binding, highlighting the power of ...
Yun‐Hsuan Kuo +3 more
wiley +2 more sources