Synthesis of long-chain alkyl and alkenyl bromides
Journal of Lipid Research, 1966 Long-chain alkyl and alkenyl bromides are obtained in quantitative yields by the reaction of methanesulfonates with anhydrous magnesium bromide in absolute ether; cis-trans isomerization of double bonds does not occur.
Wolfgang J. Baumann, Helmut K. Mangold
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Room-Temperature Alternative to the Arbuzov Reaction: The Reductive Deoxygenation of Acyl Phosphonates [PDF]
, 2010 The reductive deoxygenation of acyl phosphonates using a Wolff−Kishner-like sequence is described. This transformation allows direct access to alkyl phosphonates from acyl phosphonates at room temperature. The method can be combined with acyl phosphonate
Dougherty, Dennis A. +1 more
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Surface mobility and structural transitions of poly(n-alkyl methacrylates) probed by dynamic contact angle measurements [PDF]
, 1986 Dynamic contact angles and contact-angle hysteresis of a series of poly(n-alkyl methacrylates) (PAMA) were investigated using the Wilhelmy plate technique.
Damme, H.S. van, Feijen, J., Hogt, A.H.
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Inorganics, 2017 In contrast to alkyl compounds of lithium, which play an important role in organometallic chemistry, the corresponding heavier alkali metal compounds are less investigated.
Markus von Pilgrim +2 more
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Influence of diluent alkyl substitution on the extraction of Am(III) and Eu(III) by a 6,6’-bis(1,2,4-triazin-3-yl)-2,2’-bipyridine ligand dissolved in alkylated cyclohexanone Diluents [PDF]
, 2012 Several alkylated cyclohexanones were investigated as potential diluents for the selective extraction of Am(III) from Eu(III) from nitric acid solutions by the CyMe4-BTBP ligand.
Distler, Petr +5 more
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Inhibitory Activities of Alkyl Syringates and Related Compounds on Aflatoxin Production
Toxins, 2016 Inhibitors of aflatoxin production of aflatoxigenic fungi are useful for preventing aflatoxin contamination in crops. As methyl syringate weakly inhibits aflatoxin production, aflatoxin production inhibitory activities of additional alkyl syringates with
Tomohiro Furukawa +4 more
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Synthesis and Thermal Behaviour of Calcium Alkyl Phosphates as Bioceramic Precursors
Ceramics, 2022 Powders of alkyl phosphoric acids and calcium alkyl phosphates with various alkyl chains (butyl, octyl, and dodecyl) have been synthesized. The resulting powders were characterized by X-ray phase analysis, electron microscopy, and thermal analysis.
Andrey Tikhonov, Valery Putlayev
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Copper(0)-mediated radical polymerisation in a self-generating biphasic system [PDF]
, 2013 Herein, we demonstrate the synthesis of well-defined poly(n-alkyl acrylate)s via copper(0)-mediated radical polymerisation in a self-generating biphasic system. During the polymerisation of n-butyl acrylate in DMSO, the polymer phase separates to yield a
Amir Atme +53 more
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The alkyl moieties in wax esters and alkyl diacyl glycerols af sharks
Journal of Lipid Research, 1971 The alkyl moieties in wax esters and alkyl diacyl glycerols from the liver of the dogfish, soupfin shark, and silky shark are almost exclusively saturated and monounsaturated, the main alkyl moieties being the C16 and C18 chains in both lipid classes ...
FRIEDRICH SPENER, HELMUT K. MANGOLD
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Inorganics, 2023 A new synthetic pathway to various mono-alkyl-substituted phosphinoboranes HRP–BH2–NMe3 has been developed. The new synthetic route starting from alkyl halides and NaPH2 followed by metalation and salt metathesis is performed in a one-pot procedure and ...
Felix Lehnfeld +3 more
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