Results 221 to 230 of about 196,000 (337)

From Light‐Driven to Dark Synthesis: Streamlining Perfluoroalkyl Selenide Ether Formation

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Two orthogonal and user‐friendly protocols enable the efficient construction of (Se/S)RF bonds from simple dichalcogenides and perfluoroalkyl iodides. Visible‐light irradiation at 395 nm promotes seleno‐ and thioether formation, while a dark KOH/MeCN variant delivers selenoethers in minutes. Both approaches operate under mild, metal‐ and photocatalyst‐
Loydel Torres Barroso   +5 more
wiley   +1 more source

Switching <i>N</i>-Alkylation Regioselectivity of Trifluoromethylated Pyrazoles Guided by Functional Group Tuning. [PDF]

open access: yesInt J Mol Sci
Edilova YO   +6 more
europepmc   +1 more source

Photochemical Amination of Thioethers Under Biphasic Flow Conditions

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Biphasic reaction conditions for the iron‐catalyzed synthesis of sulfilimines and sulfoximines in continuous flow using 2,2,2‐trichloroethyl‐N‐mesyloxycarbamate (TrocNHOMs). A practical, continuous flow, biphasic photochemical amination of thioethers, employing N‐mesyloxycarbamates as nitrene precursors, is reported. Using UVA irradiation at 365 nm and
Calvine Lai, Hélène Lebel
wiley   +1 more source

Review of Transcriptomic Biomarkers That Predict In Vitro Genotoxicity in Human Cell Lines

open access: yesEnvironmental and Molecular Mutagenesis, EarlyView.
ABSTRACT The current genotoxicity testing paradigm provides little mechanistic information, has poor specificity in predicting carcinogenicity in humans, and is not suited to assessing a large number of chemicals. Genomic technologies enable the characterization of genome‐wide transcriptional changes in response to chemical treatments that can inform ...
Heng‐Hong Li   +7 more
wiley   +1 more source

Enhanced Hydrogenation of Cyclohexanone: A Multi‐Scale Investigation Into Noncatalytic and Catalytic Pathways Towards Sustainable Conversion

open access: yesEnergy Science &Engineering, EarlyView.
ABSTRACT The selective hydrogenation of oxygenated compounds is crucial for the conversion of biocrude into platform chemicals. However, the presence of stable oxygenated species, cyclohexanone, in biocrude limits possess a challenge for easy conversion process.
Ishaq Kariim   +4 more
wiley   +1 more source

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