From Light‐Driven to Dark Synthesis: Streamlining Perfluoroalkyl Selenide Ether Formation
Two orthogonal and user‐friendly protocols enable the efficient construction of (Se/S)RF bonds from simple dichalcogenides and perfluoroalkyl iodides. Visible‐light irradiation at 395 nm promotes seleno‐ and thioether formation, while a dark KOH/MeCN variant delivers selenoethers in minutes. Both approaches operate under mild, metal‐ and photocatalyst‐
Loydel Torres Barroso +5 more
wiley +1 more source
Switching <i>N</i>-Alkylation Regioselectivity of Trifluoromethylated Pyrazoles Guided by Functional Group Tuning. [PDF]
Edilova YO +6 more
europepmc +1 more source
Nitro-fatty acids are formed in response to virus infection and are potent inhibitors of STING palmitoylation and signaling [PDF]
Miner, Cathrine A. +2 more
core +1 more source
Photochemical Amination of Thioethers Under Biphasic Flow Conditions
Biphasic reaction conditions for the iron‐catalyzed synthesis of sulfilimines and sulfoximines in continuous flow using 2,2,2‐trichloroethyl‐N‐mesyloxycarbamate (TrocNHOMs). A practical, continuous flow, biphasic photochemical amination of thioethers, employing N‐mesyloxycarbamates as nitrene precursors, is reported. Using UVA irradiation at 365 nm and
Calvine Lai, Hélène Lebel
wiley +1 more source
Co<sub>3</sub>O<sub>4</sub>‑Promoted Cerium Oxide Catalyst for Efficient Catalytic <i>N</i>‑Alkylation of Amines with Alcohols. [PDF]
Kou J +6 more
europepmc +1 more source
Beyond Alkylation – Cyclophosphamide's Expanding Role in Cancer Therapy and Immunomodulation
Mohalkar Krushna*, Dahatonde Abhijit, Munfan Sumit, Dr. Tarde Vijay
openalex +1 more source
Review of Transcriptomic Biomarkers That Predict In Vitro Genotoxicity in Human Cell Lines
ABSTRACT The current genotoxicity testing paradigm provides little mechanistic information, has poor specificity in predicting carcinogenicity in humans, and is not suited to assessing a large number of chemicals. Genomic technologies enable the characterization of genome‐wide transcriptional changes in response to chemical treatments that can inform ...
Heng‐Hong Li +7 more
wiley +1 more source
Iron photocatalysis towards site-selective C(sp<sup>3</sup>)-H alkylation of glycines and peptides. [PDF]
Panda SP +4 more
europepmc +1 more source
ABSTRACT The selective hydrogenation of oxygenated compounds is crucial for the conversion of biocrude into platform chemicals. However, the presence of stable oxygenated species, cyclohexanone, in biocrude limits possess a challenge for easy conversion process.
Ishaq Kariim +4 more
wiley +1 more source
Biocatalytic Enantioselective Oxidation of <i>N</i>-Acyl-<i>S</i>-Methyl Sulfenamides for the Asymmetric Synthesis of <i>S</i>-Methyl Sulfoximines. [PDF]
Patel S +4 more
europepmc +1 more source

