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Catalytic alkylation of unactivated C(sp3)-H bonds for C(sp3)-C(sp3) bond formation.
Chemical Society Reviews, 2019The construction of carbon-carbon bonds is a central tenet of modern synthetic chemistry. Metal-catalyzed C-H functionalization can serve as a particularly powerful tool for achieving carbon-carbon bond formation.
Zhen Chen +5 more
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Journal of the American Chemical Society, 2019
The asymmetric allylic alkylation (AAA), which features employing active allylic substrates, has historical significance in organic synthesis.
Hua-Chen Lin +8 more
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The asymmetric allylic alkylation (AAA), which features employing active allylic substrates, has historical significance in organic synthesis.
Hua-Chen Lin +8 more
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Chemoselective N-alkylation of Indoles in Aqueous Microdroplets.
Angewandte Chemie, 2019Many reactions show much faster kinetics in microdroplets than that in the bulk phase. Most reported reactions in microdroplets mirror the products found in bulk reactions.
E. Gnanamani, Xin Yan, R. Zare
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Sequence-Dependent Stereodivergent Allylic Alkylation/Fluorination Reaction of Acyclic Ketones.
Angewandte Chemie, 2019The stereodivergent Ir-catalyzed allylic alkylation and fluorination of acyclic ketones is described. α -Pyridyl- α -fluoroketones with vicinal tertiary and quaternary stereocenters were obtained in moderate to excellent yields and stereoselectivities ...
Xi‐Jia Liu +5 more
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