Results 91 to 100 of about 66,858 (295)
Pinwheel-like Curved Aromatics from the Cyclotrimerization of Strained Alkyne Cycloparaphenylenes [PDF]
Curved aromatic hydrocarbons often display better solubility and more desirable electronic properties in comparison to their flat counterparts. Macrocyclic curved aromatics possess these traits as well as shape-persistent pores ideal for host-guest ...
Lev, Zakharov +4 more
core +2 more sources
2D Abrupt Nano‐Junctions Blending sp–sp2 Bonds on Atomically Precise Heterostructures
Advanced Materials, EarlyView.A lateral heterostructure between atomically precise sp–sp2$^2$ metalated graphdiyne and sp2$^2$ graphene nanoribbons is realized by on‐surface synthesis and investigated by STM and DFT. The impact of on‐surface synthesis byproducts on covalent junction formation yield is unveiled.
Alice Cartoceti +10 more
wiley +1 more source
Ambient gold-catalyzed O-vinylation of cyclic 1,3-diketone: A vinyl ether synthesis
Beilstein Journal of Organic Chemistry, 2013 Gold-catalyzed O-vinylation of cyclic 1,3-diketones has been achieved for the first time, which provides direct access to various vinyl ethers.
Yumeng Xi, Boliang Dong, Xiaodong Shi
doaj +1 more source
Poly(Alkoxythiophene) Rod‐Coil Block Copolymers for Organic Electrochemical Transistors
Advanced Materials, EarlyView.We present the first synthesis of poly(3‐alkoxythiophene) rod‐coil block copolymers as a new architecture for OMIECs. Incorporating PEG and PLLA coils can enhance device performance beyond the homopolymer. The figure‐of‐merit depends uniquely on coil length.
Junfu Tian +23 more
wiley +1 more source
Iodine-Catalyzed Carbonyl-Alkyne Metathesis Reactions [PDF]
The reaction between aldehydes or ketones and alkynes –the carbonyl-alkyne metathesis– constitutes a very useful strategy for the synthesis of ,-unsaturated carbonyls.
Martin, Breugst, Thiemo, Arndt
core +2 more sources
Advanced Materials Interfaces, EarlyView.This study proposes a function‐sharing anode design to enable nonmetallic lithium insertion while maintaining intimate interfacial contact with the solid‐state electrolyte. A combination of lithium‐compatible and conformable borohydrides, highly conformable indium metal, less‐graphitized acetylene black, and a layer of highly graphitized massive ...
Keita Kurigami +3 more
wiley +1 more source
Journal of the Brazilian Chemical Society, 2003 The co-ordination of FcCCC6H4-4-NO2 (1) to a ruthenium carbonyl cluster to yield [Ru3(mu 3-FcCCC6H4-4-NO2) (mu-dppm)( mu-CO)(CO)7] (2) is reported. The cyclic voltammograms of these compounds and of the analogous clusters [Ru3(mu3 -eta2-C6 H5CCC6H4-4-R ...
Rosseto Renato +3 more
doaj
Design, Synthesis and Characterization of Novel Isoxazole Tagged Indole Hybrid Compounds
Open Chemistry, 2020 Sixteen new isoxazole tagged indole compounds have been synthesized via copper (I) catalyzed click chemistry of the aryl hydroxamoyl chloride and an indole containing alkyne moiety. The chemical structure of the synthesized compounds has been established
Al-Qawasmeh Raed A. +6 more
doaj +1 more source
Advanced Science, EarlyView.ABSTRACT Breast cancer remains one of the most prevalent malignancies among women, and taxane‐based chemotherapies such as paclitaxel and docetaxel are central to standard treatment regimens. However, drug resistance in breast cancer limits therapeutic efficacy and contributes to recurrence and metastasis.
Kai Wang +7 more
wiley +1 more source
Total Synthesis of Chiral Falcarindiol Analogues Using BINOL-Promoted Alkyne Addition to Aldehydes
Molecules, 2016 An enantioselective total synthesis of chiral falcarindiol analogues from buta-1,3-diyn-1-yltriisopropylsilane is reported. The key step in this synthesis is BINOL-promoted asymmetric diacetylene addition to aldehydes.
Li Wang +7 more
doaj +1 more source