Results 71 to 80 of about 68,808 (283)

Crystal structure, Hirshfeld surface analysis and interaction energy and DFT studies of 2-chloroethyl 2-oxo-1-(prop-2-yn-1-yl)-1,2-dihydroquinoline-4-carboxylate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2019
The title compound, C15H12ClNO3, consists of a 1,2-dihydroquinoline-4-carboxylate unit with 2-chloroethyl and propynyl substituents, where the quinoline moiety is almost planar and the propynyl substituent is nearly perpendicular to its mean plane.
Sonia Hayani   +6 more
doaj   +1 more source

Alkyne-Tagged PLGA Allows Direct Visualization of Nanoparticles In Vitro and Ex Vivo by Stimulated Raman Scattering Microscopy

open access: yes, 2019
Polymeric nanoparticles (NPs) are attractive candidates for the controlled and targeted delivery of therapeutics in vitro and in vivo. However, detailed understanding of the uptake, location, and ultimate cellular fate of the NPs is necessary to satisfy ...
Martin Lee (4786263)   +15 more
core   +1 more source

-alkyne) Complexes of Highly Polarized Alkynes [PDF]

open access: yes, 2013
The solid state structures of the cobalt-alkyne complexes (η5-C5H5)(PPh3) Co{η2-(R3Si)Cî - C(SO2Ar)} (3-TMS, R = Me, Ar = C6H5; 3-TIPS, R = CH(CH3) 2, Ar = p-C6H4CH3) and the noncoordinated alkyne (Me3Si)Cî - C(SO2Ph) (6-TMS) have been characterized by X-
Baldridge, Kim K   +20 more
core   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

open access: yesAdvanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen   +7 more
wiley   +1 more source

Poly(Alkoxythiophene) Rod‐Coil Block Copolymers for Organic Electrochemical Transistors

open access: yesAdvanced Materials, EarlyView.
We present the first synthesis of poly(3‐alkoxythiophene) rod‐coil block copolymers as a new architecture for OMIECs. Incorporating PEG and PLLA coils can enhance device performance beyond the homopolymer. The figure‐of‐merit depends uniquely on coil length.
Junfu Tian   +23 more
wiley   +1 more source

Single‐Particle FRET Probes Heterogeneity in the Ligand Shell of Colloidal Perovskite Quantum Dots

open access: yesAdvanced Materials, EarlyView.
Single‐particle, single‐molecule Förster resonance energy transfer turns dye‐tagged ligands into nanorulers for the otherwise elusive organic shell of CsPbBr3 quantum dots. Distance variations within individual particles reveal pronounced local heterogeneity, while changes in the surrounding ligand chemistry shift the average dye–surface separation ...
Leon G. Feld   +6 more
wiley   +1 more source

Design of High‐Energy Anode for All‐Solid‐State Lithium Batteries–A Model with Borohydride‐Based Electrolytes

open access: yesAdvanced Materials Interfaces, EarlyView.
This study proposes a function‐sharing anode design to enable nonmetallic lithium insertion while maintaining intimate interfacial contact with the solid‐state electrolyte. A combination of lithium‐compatible and conformable borohydrides, highly conformable indium metal, less‐graphitized acetylene black, and a layer of highly graphitized massive ...
Keita Kurigami   +3 more
wiley   +1 more source

Engineering Microbial Particles for Next‐Generation Biomedical Platforms

open access: yesAdvanced Science, EarlyView.
Microbe‐derived particles (MDPs), which include extracellular vesicles, outer membrane vesicles, inclusion bodies, polysaccharide particles, and virus‐like particles, represent a rapidly expanding category of bioinspired nanomaterials. With their natural origin, intrinsic biocompatibility, and highly programmable functionality, MDPs serve as a ...
Yuting Li   +7 more
wiley   +1 more source

Electrolyte–Framework Matching in High‐Voltage TEMPO‐COF Cathodes for Lithium Batteries

open access: yesAdvanced Science, EarlyView.
TEMPO‐functionalized covalent organic frameworks are investigated as high‐voltage cathodes for lithium batteries. Screening five electrolyte anions identifies lithium difluoro(oxalato)borate (LiDFOB) as the optimal electrolyte, balancing capacity, rate capability, and cycling stability, while buckypaper electrodes achieve high mass loading (40 mg cm−2)
Marilyn Esclance DMello   +5 more
wiley   +1 more source

Regioselective alkynylation followed by Suzuki coupling of 2,4-dichloroquinoline: Synthesis of 2-alkynyl-4-arylquinolines

open access: yesBeilstein Journal of Organic Chemistry, 2009
A two step synthesis of 2-alkynyl-4-arylquinolines has been accomplished via Pd/C-mediated regioselective C-2 alkynylation of 2,4-dichloroquinoline in water followed by Suzuki coupling at C-4 of the resulting 4-chloro derivative.
Ellanki A. Reddy   +5 more
doaj   +1 more source

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