Gold-Catalyzed Cyclizations of 4-Alkyl-2-yn-1-yl (Oxy)cyclohexa-2,5-dien-1-ones (1) to Develop Two Cyclizations via π-Alkyne versus π-Allene Activations. [PDF]
Kshirsagar AS, Liao PQ, Yang T, Liu RS.
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Rh‐catalyzed chemodivergent parallel kinetic resolution of racemic 1,6‐enynes with α‐fluoroacrylamides or mixtures of different acrylamides proceeded via [2+2+2] cycloaddition and C–H alkylation to afford structurally and stereochemically distinct products with high selectivity under mild conditions.
Shintaro Hamada +5 more
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Outcompeting hydrofunctionalization: Asymmetric remote substitution of alkynes. [PDF]
Shen YX, Ma C, Lin GQ, He ZT.
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Development and Optimization of an Aminooxy Coupling Reaction to Prepare Multivalent Bioconjugates with a Single Noncanonical Amino Acid. [PDF]
Gourdie RK +12 more
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Functional group tolerant iron-catalyzed cyclotrimerization of terminal and internal alkynes. [PDF]
Klinnert B, Plietker B.
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Synthesis of Selaginpulvilin D by [2 + 2 + 2] Cyclotrimerization─A Second-Generation Approach. [PDF]
Nallappan S, Rycek L.
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Profiling the proteome-wide selectivity of diverse electrophiles. [PDF]
Zanon PRA +14 more
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ASCT2 palmitoylation regulated by JNK1-ZDHHC14 axis orchestrates glutamine metabolism and NSCLC progression. [PDF]
Chen X +14 more
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Versatility of Click Chemistry in Hydrogel Synthesis: From Molecular Strategies to Applications in Regenerative Medicine. [PDF]
Carrascal-Hernández DC +4 more
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Dimesitylphosphide as a heavier congener of established amide ligands for charge‐transfer copper(I) complexes leads to bathochromic shift of the emission by up to 3645 cm−1 into the orange‐red (solid, polymer films) and even NIR (solution). The thermally activated delayed fluorescence exhibits high dissymmetry factors of glum = 10−2 in polystyrene.
Paul C. Ruer +2 more
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