Results 161 to 170 of about 68,808 (283)

Diamondiyne: A 3D Carbon Allotrope With Mixed sp–sp3 Hybridization

open access: yesAngewandte Chemie, EarlyView.
A new carbon allotrope with mixed sp–sp3 hybridization has been synthesized through delicately controlled kinetics at a liquid–liquid interface. The resulting material, termed diamondiyne, exhibits an expanded diamond‐type network in the form of small crystallites in a continuous all‐carbon film.
Yizhou Yang   +12 more
wiley   +2 more sources

A Mild Disilane‐Enabled Halide‐to‐Deuterium Manifold With D2O for Aryl and Benzylic Halides

open access: yesAngewandte Chemie, EarlyView.
A broadly applicable Pd‐catalyzed dehalogenative deuteration enables efficient conversion of aryl and benzylic halides with inexpensive deuterium oxide (D2O). The method proceeds under exceptionally mild conditions without strong bases, harsh reductants, or stoichiometric Lewis acid halide scavengers, and tolerates a wide range of functional groups ...
Wenliang Wang   +5 more
wiley   +2 more sources

Evidence for a Cu(II)-Catalysed CuAAC Reaction: A Combined Experimental and Computational Study. [PDF]

open access: yesAngew Chem Int Ed Engl
Andrews MJ   +12 more
europepmc   +1 more source

One‐Pot Biphasic Photocatalytic CO2‐to‐Carbonylation Cascades

open access: yesAngewandte Chemie, EarlyView.
Bioinspired biphasic compartmentalization enables one‐pot cascades where photocatalytic CO2 reduction generates CO for carbonylative cross‐couplings to synthesize complex organic products, including a pharmaceutical. ABSTRACT Photosynthesis compartmentalizes reactions across the thylakoid membrane in vivo to upcycle CO2 into complex chemicals that are ...
Sampurna Mitra   +3 more
wiley   +2 more sources

Catalytic Stereoselective Intermolecular Fluoroacylation of Unactivated Alkynes via C-F Bond Reconstruction. [PDF]

open access: yesOrg Lett
Kanji T   +6 more
europepmc   +1 more source

Functionalization and Metal Ion Encapsulation Within a Triaxial Supramolecular Weave

open access: yesAngewandte Chemie, EarlyView.
The functionalization of a triaxially woven supramolecular weave was achieved. Pre‐assembly modification of the peptide‐perylene monoimide building block enabled facile and homogeneous introduction of acetyl, pivaloyl and thiophene moieties throughout the assembly without disrupting the woven structure.
Andreas Herdlitschka   +6 more
wiley   +1 more source

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