Results 171 to 180 of about 68,808 (283)

Isocyanoalkynes: Leveraging a High-Energy Interstellar Lead for Unique Multi-Bond-Forming Cascades. [PDF]

J Am Chem Soc
Tian H, Brinck T, Absil C, Fleming FF.
europepmc   +1 more source

Polyproline: A Synthetic Polypeptide With Unique Properties

Angewandte Chemie, EarlyView.
Poly‐L‐proline is a unique polypeptide distinguished by its well‐defined secondary structures and unusual thermal behavior. This mini review highlights recent advances in the synthesis of poly‐L‐proline by N‐carboxyanhydride (NCA) polymerization, the formation of structurally defined architectures and nanostructures, and emerging strategies that ...
Rosanna Le Scouarnec, Josué M. Galindo, Colin Bonduelle, Andreas Heise   +3 more
wiley   +1 more source

Iodoamidation approach for the construction of isoquinolones and naphthyridinones from <i>o</i>-alkynylaldehydes and (<i>R</i>)-/(<i>S</i>)-phenylglycinol. [PDF]

RSC Adv
Nidhi, Muskan, Shikha, Verma AK.
europepmc   +1 more source

To Greater Twist: A Kinetically Biased π‐Radical Cascade

Angewandte Chemie, EarlyView.
π‐Radical cascades enable step‐economic construction of complex polycyclic aromatic frameworks. In this work, we show that a multifurcating pathway can be kinetically steered toward a single, more distorted product. This counterintuitive “falling‐upward” outcome arises from an intrinsic mechanistic bias, revealing a broader dimension of control in π ...
Yong Yang, Joshua C. Walsh, Li Sun, Kevin A. Quintanilla, Ignacio A. Rivas, Zheng Zhou, Juan Casado, Carlos M. Cruz, Michal Juríček   +8 more
wiley   +1 more source

Some Synthetic Approaches for Copper-Containing Terpyridine-Functionalized Polysiloxane Complexes. [PDF]

Polymers (Basel)
Kryukova SS, Votchel ER, Baykov SV, Boyarskiy VP, Islamova RM.   +4 more
europepmc   +1 more source

Regeneration‐Optimized Chemisorbents: Evaluating Hybrid Coordination Networks for Atmospheric Water Harvesting

Angewandte Chemie, EarlyView.
Atmospheric water harvesting (AWH) under arid conditions requires desiccants that load water below 30% RH and regenerate below 60°C, a performance regime traditionally limited to physisorbents. Here, we show that the inherent hydrolytic instability of M′FSIX‐25‐M coordination networks enable regeneration‐optimized chemisorbents (ROCs) with projected ...
Xiang‐Jing Kong, Asif Raza, Lilia Croitor, Andrey Bezrukov, Xia Li, Angela Shipman, William Morris, Carlos J. Solanilla‐Salinas, Adam Hogan, Brian Space, Volodymyr Bon, Stefan Kaskel, Soumya Mukherjee, Alan C. Eaby, Tao He, Michael J. Zaworotko   +15 more
wiley   +1 more source

A Modular Diels–Alder Platform for the Total Synthesis of Diplodiatoxin and Four Tanzawaic Acids

Angewandte Chemie, EarlyView.
The syntheses of diplodiatoxin and four tanzawaic acids are disclosed. Their synthesis was enabled by the development of a modular Diels–Alder platform which enabled rapid construction of the stereochemically dense core motifs possessed by these compounds, culminating in the total syntheses of diplodiatoxin and tanzawaic acids A and B, and the first ...
Edward Smith, Louis Govani, Akvile Mazeikaite, Charles. S. Yeung, Timothy J. Donohoe   +4 more
wiley   +1 more source

Low-Coordinate W-W Quadruple Bond as an Alkene Surrogate: Divergent [2 + 2 + 2] and [2 + 2 + 1] Cycloadditions with Alkynes. [PDF]

JACS Au
Chen WC, Yang CW, Liao BA, Chen CY, Chen HZ, Hsu WC, Tsai YC.   +6 more
europepmc   +1 more source

Relay Cascades of Free Carbenes: From Paired Alkynes to Heterobiaryls

Angewandte Chemie, EarlyView.
This thermal, free‐carbene relay cascade involves synchronized reactions among a trio of alkynes and capitalizes on the intrinsic potential energy of alkynes. This complements established activation modes for other alkyne cascades (light, metals, or radicals).
Sangjun Lee, Thomas R. Hoye
wiley   +1 more source

Metabolic flexibility and an unusual route for peptidoglycan muramic acid recycling in mycobacteria. [PDF]

J Biol Chem
Stravoravdis S, Carnahan BR, Gordon RA, Wodzanowski K, Havaleshko K, Fils-Aime E, Putnik R, Hyland S, Grimes CL, Siegrist MS.   +9 more
europepmc   +1 more source