Results 201 to 210 of about 90,721 (285)

Hydrogen Activation via Dihydride Formation on a Rh1/Fe3O4(001) Single‐Atom Catalyst

open access: yesAngewandte Chemie International Edition, EarlyView.
Deuterium (hydrogen) adsorption on single‐atom Rh1/Fe3O4(001) catalyst does not induce D (H) spillover onto the reducible Fe3O4 support. Instead, a Rh1‐dihydride (Rh−2D or Rh−2H) species forms and D2 or H2desorbs during annealing. ABSTRACT Hydrogen activation is a key elementary step in catalytic hydrogenation.
Chunlei Wang   +12 more
wiley   +1 more source

A Dithio Vinylthio C2 Synthon Enabling Crystalline and Luminescent Sulfur‐Decorated Polymers

open access: yesAngewandte Chemie International Edition, EarlyView.
Transforming CaC2 into a modular C2 building block enables the synthesis of α,ω‐bis(vinylthio) monomer and its conversion into crystalline, sequence‐defined sulfur‐decorated polymers. Their dense thioether clustering induces nonconventional luminescence and provides structure–function control in a more‐sustainable polymer platform.
Bercis Pektas   +4 more
wiley   +1 more source

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